background: a new microextraction method named dispersive liquid-liquid microextraction (dllme) for determination of chloroform in pool water and blood of swimmers after swimming is described. methods: this method was performed based on coupling dispersive liquid-liquid microextraction (dllme) with gas chromatog­raphy-mass spectrometry (gc-ms). methanol and trichloroethylenes were used as the d...

dispersive liquid liquid microextraction (dllme) combined with gas chromatography–mass spectrometry (gc–ms) was used for the extraction and determination of 13 polycyclic aromatic hydrocarbons (pahs) in mineral water samples. in this procedure, the suitable combination of extraction solvent (500 µl chloroform) and disperser solvent (1000 µl acetone) were quickly injected into the water sample (...

a new simple and rapid dispersive liquid-liquid microextraction has been applied to preconcentrate tracelevels of zinc as a prior step to its determination by spectrophotometric method. in the proposed method, 4-(2-pyridylazo) resorcinol (par) is used as a chelating agent, and chloroform and ethanol are selected asextraction and dispersive solvent. the optimization strategy is carried out by us...

in this research, a rapid, reliable and selective dispersive liquid-liquid microextraction (dllme) followed by direct injection of microdroplet to graphite furnace atomic absorption spectrometry (gf-aas) method for the determination of ultra-trace amounts of ag(i) was developed. effect of the important experimental parameters on the extraction efficiency of ag(i) was investigated using response...

Phthalate esters are endocrine disrupters or mutagens. They are widely used as plasticizers and can be usually found in environmental samples, such as food, soil and polluted air. However, it is difficult to directly determine phthalate esters owing to their relatively low concentration and complex matrices. Therefore, preconcentration and separation have become increasingly important. In recen...

This paper would like to compare two extraction procedures for analyzing phthalates (PAEs) in hot drinks collected at vending machines, usually coffee and tea. The analytical are based on Solid Phase Extraction (SPE) using C18 cartridge dispersive liquid-liquid microextraction (DLLME) assisted by ultrasound vortex improving the dispersion mechanically, with each followed a routinary method such...

The review of the RP HPLC analysis of basic psychotropic drugs is presented. It contains sample preparation methods with centrifugation, protein precipitation, liquid-liquid extraction (LLE), dispersive liquid-liquid microextraction (DLLME), solid-phase extraction (SPE), solid-phase microextraction (SPME), microwave-assisted extraction (MAE) and RP-HPLC analysis. Chromatographic behavior of bas...

Abbreviations: AIBN, 2,20-azo-bis-isobutyronitrile; ASE, Accelerated solvent extraction; CAR, Carboxen; DAD, Diode-array detector; DI-SPME, Direct-immersion solid-phase extraction; DSPE, Dispersive solid-phase extraction; EGDMA, Ethylene glycol dimethacrylate; ESE, Enhanced solvent extraction; ESI, Electrospray ionization; FD, Fluorescence detection; FLD, Fluorimetric detection; GC, Gas chromat...