A mixing rule for the mixtures of hard-spheres is presented which can be reduced to the standard van der Waals mixing rule at low densities. The effectiveness of the mixing rule for the size and energy parameters of lennard-Jones fluid are examined by combining them with an equation of state to calculate thermodynamic properties. The results of calculation are compared with the molecular dy...

Among the intermolecular interactions, the Casimir and van der Waals forces are the most important forces that highly affect the behavior of nanostructures. This paper studies the effect of such forces on the adhesion of cantilever freestanding nanostructures. The nanostructures are made of a freestanding nano-beam which is suspended between two upper and lower conductive surfaces. The linear s...

This paper explores the mechanism of bending with kinking of a long single-walled carbon nanotube under pure bending with moderate bending angles. The prebuckling response was modeled using the existing continuum mechanics theory accounting for the ovalization of the cross section. The post-buckling behavior was characterized by the development of an elastic kink mechanism, considering the van ...

Fine powders often tend to agglomerate due to van der Waals forces between the particles. These forces can be reduced significantly by covering the particles with nanoscaled adsorbates, as shown by recent experiments. In the present work a quantitative statistical analysis of the effect of powder flow regulating nanomaterials on the adhesive forces in powders is given. Covering two spherical po...

The force field used was MMF94s, without any solvent treatment. A constant dielectric of 1.0 was employed for the electrostatic treatment, whereas the charges were assigned by the force field (Fig. 1). Moreover, an extended non-bonded cut-off was set, for taking into account the best maximum distances over which hydrogen bonding, Van der Waals and electrostatic contributions to the molecular po...

We present a new approach to calculate the attractive long-range vortex-vortex interaction of the van der Waals type present in anisotropic and layered superconductors. The mapping of the statistical mechanics of two-dimensional charged bosons allows us to define a Casimir problem: Two half spaces of vortex matter separated by a gap of width R are mapped to two dielectric half planes of charged...

Encouraged by recent advances in revealing significant effects of van der Waals wells on reaction dynamics, many people assume that van der Waals wells are inevitable in chemical reactions. Here we find that the weak long-range forces cause van der Waals saddles in the prototypical C(1D)+D2 complex-forming reaction that have very different dynamical effects from van der Waals wells at low colli...

All bodies are surrounded by a fluctuating electromagnetic field due to thermal and quantum fluctuations of the current density inside the bodies. This fluctuating field is responsible for many important phenomena such as the radiative heat transfer, the van der Waals interaction and the van der Waals friction between bodies. In contrast to the van der Waals interaction, for which theory is wel...

Articles you may be interested in Isobaric first-principles molecular dynamics of liquid water with nonlocal van der Waals interactions A simplified implementation of van der Waals density functionals for first-principles molecular dynamics applications J. Density, structure, and dynamics of water: The effect of van der Waals interactions van der Waals isomers and ionic reactivity of the cluste...

We investigate the effect of monopolar charge disorder on the classical fluctuation-induced interactions between randomly charged net-neutral dielectric slabs and discuss various generalizations of recent results [A. Naji et al., Phys. Rev. Lett. 104, 060601 (2010)] to highly inhomogeneous dielectric systems with and without statistical disorder correlations. We shall focus on the specific case...