Background: Ornithine (Orn) plays an essential role in the metabolism of plant cells through incorporation in polyamines biosynthesis, the urea cycle and nitrogen metabolism. Physiological response of the plant cells to its two enantiomers have not been widely investigated yet.Objectives: This study aimed to evaluate effect of ornithine enantiomers on exp...

The structures, interaction energies, vibrational analysis, and electronic properties for different urea-hydrogen peroxide (UHP) 1:1 complexes have been studied. Density functional theory (DFT) using the B3LYP hybrid exchange-correlation functional was employed to characterize five new cyclic structures in addition to the experimental one. The basis sets used were Dunning’s correlation consiste...

Catalytic buffering is an advanced method of pH control for the enzyme-based Advanced Catalytic Enzyme System (ACES) and oxidative surety agent decontamination technologies. Ammonia production from urea by urease neutralizes the production of Oalkylphosphonic acids resulting from the hydrolysis of Nerve agents such as Sarin and VX. Fluoride production from Sarin hydrolysis inhibits native ureas...

To explore the possibility of using graphene based biosensor, adsorption of hydrogen peroxide on graphene has been investigated using density functional theory. The electronic properties of defect free and defective graphene in the presence of different number of hydrogen peroxide have been studied. The graphene with the most stable configuration defect named as SW defect is considered. The hig...

drought is one of the important environmental stresses that reduce the crop growth. oxidative stress is a secondary stress due to drought and other abiotic stresses. in order to study the effect of exogenous application of hydrogen peroxide on drought tolerance of glob amaranth (gomphrena globosa l.), an experiment was conducted in greenhouse conditions. this study was designed as factorial bas...

salinity is one of the environmental stresses that have limited influence on the crop growth. oxidative process is a secondary stress due to salinity. oregano is enumerated as one of the most important of medicinal plant that its production and development is possible in iran. in order to study the effect of exogenous application of hydrogen peroxide on salt tolerance in oregano (origanum major...

The oxidation of isatins at room temperature, using the cheap and environmentally friendly urea-hydrogen peroxide complex and ultrasonic irradiation, has been investigated. The ultrasonic irradiation dramatically reduces the reaction time. With easy and reproducible reaction procedures, different isatoic anhydrides were obtained in excellent yield and with high purity.