Intramolecular cyclic etherification of 1,3-diols was investigated using iodine as a catalyst under solution reaction conditions. Compounds containing five-membered ether rings were obtained. Propella ether (11-oxatricyclo[4.4.3.0(1,6)]tridecane) was conveniently synthesized from 1,3-diol (6-(2-hydroxyethyl)spiro[4.5]decan-6-ol) in 97% yield via carbon skeleton rearrangement. Spiroethers and bi...

Phase separation in mixtures of polymers and alkanes is investigated with the aid of a recently developed lattice model, based on the Born-Green-Yvon (BGY) integral equation approach to fluids. The system-dependent parameters of the BGY lattice model for binary mixtures are deduced from those of its pure components, which in turn are determined from a comparison with experimental data. The lowe...

Due to their architectural intricacy and biological significance, the synthesis of polycyclic diterpenes and their biogenetically related alkaloids have been the subject of considerable interest over the last few decades, with progress including the impressive synthesis of several elusive targets. Despite tremendous efforts, conquering the unique structural types of this large natural product f...

The chelating behavior of the thiosemicarbazone derivatives of 2-hydroxy-8-R-tricyclo[7.3.1.0.(2,7)]tridecane-13-one (where R = H, CH3, C6H5) towards Co(II), Ni(II) and Cu(II) has been investigated by elemental analysis, molar conductivity measurements, UV-VIS, IR, ESR spectroscopy and thermal studies. It was deduced from the experiments performed that the ligands coordinate to metal ions in di...

Abstract Hydrometers are widely used in industry for liquid density measurement. It is important to achieve rapid and high accuracy calibration hydrometers. Based on the Archimedes principle, a fully automatic hydrometer system NIM was designed using Cuckow’s method. The of n -tridecane (C 13 H 28 )is calibrated with 441 g high-purity fused silica ring as solid standard. buoyancy measured by st...

the genus tanacetum l. is one of the most important medicinal plant that contains 28 species in iran, 12 of them are endemics. this paper reports the essential oil composition of tanacetum hololeucum (bornm.) podlech; tanacetum kotschyi (boiss.) grierson, growing wild in iran. plant flowers were collected from different zones of dizin in north of iran. all samples were hydro-distilled (clevenge...

The biological and organoleptic properties of Bulgarian yogurt are largely determined by the metabolic activity selected strains Lactobacillus delbrueckii ssp. bulgaricus. HS-SPME-GC-MS technique was used to analyze volatile compounds produced following strains: bulgaricus MG1, MG2, MG3 MG4, MG5 MG6, MG7 MG8. A study optimize conditions SPME performed. optimum extraction aromatic components obt...