For spectrophotometric analysis of Hg (II) ions, we have used and compared two membranes preparation methods using different polymer; one is poly(vinyl chloride) (PVC) and the other is triacetylcellulose (TAC). In the case of TAC membrane, it was treated with a ligand solution (1.166 × 10-3 mole L-1) in ethylenediamine at the ambient temperature for almost 2-5 min. However, in the case of PVC m...