A sol-gel process starting with tin tetrachloride and ethylene glycol as precursors, has been successfully used to prepare nanostructured tin oxide powders. The molecular structure evolution during the process has been identified using infrared spectroscopy and the underlying reaction mechanisms of the sol-gel process are proposed. Results suggest that the -OHCH2CH2OHprevent Cl− ions from acces...

the aim of this research is preparation of sno2 nanowires by means of thermal chemical reaction vapor transport deposition (tcrvtd) method from sno powders. the morphology, chemical composition and microstructure properties of the nanowires are characterized using field emission scanning electron microscope (fe-sem), eds, and xrd. the xrd diffraction patterns reveal that the sno2 nanowires have...

Titanium nitride (TiN) is one of the most well-established engineering materials nowadays. TiN can overcome most of the drawbacks of palsmonic metals due to its high electron conductivity and mobility, high melting point and due to the compatibility of its growth with Complementary Metal Oxide Semiconductor (CMOS) technology. In this work, we review the dielectric function spectra of TiN and we...

Along with high sensitivity in detecting gas, the response and recovery times of semiconductor gas sensors are of considerable importance for real life applications. In most cases, the recovery time is more than the response time. At the same time, water vapor present in the ambient, is chemisorbed on the tin oxide, SnO2 surface and the water molecules dissociate into hydroxyl species, which ac...

Surface analysis techniques have been used to investigate tin oxide-coated soda lime glass specimens prior and subsequent to their exposure to DC bias, heat, and humidity. All specimens reported here comprise the following layered structure: tin oxide/silicon oxycarbide/glass. Depth profiling using X-ray photoelectron spectroscopy (XPS) clearly shows the interfacial regions in both control samp...

gas sensitive metal oxide layers used in fabrication of resistive gas sensors are prepared by different deposition techniques. the technical data reported on some basic and practically important specifications of these devices, although fabricated based on the same gas sensitive oxide, are anomalously different. the influence of the fabrication technique used for the deposition of the gas sensi...

double layer zno/sno2 thin film resistive gas sensors were fabricated by successive pvd of those oxides onto porcelain substrates. the metallic contacts were provided by electron beam evaporation of platinum onto substrates prior to deposition of the gas sensitive layers. deposits were thermally annealed at different temperatures. it was shown that the activation energy of electrical conduction...

A composite polymer surface coated on a tin oxide offers dramatic improvement in the stability and sensitivity of voltammetric measurement of pyridostigmine bromide as compared to individual tin oxide, polyaniline or polypyrrole coated electrode. A linear current response was achieved with a detection limit of 1x10 M. The stability and morphology of the polymer surfaces were determined by therm...

We report a deposition of the tin oxide/hydroxide nanostructured layer by the potentiodynamic method from acidic nitrate solutions directly over the substrate, equipped with multiple strip electrodes which is employed as a gas-analytical multisensor array chip. The electrochemical synthesis is set to favor the growth of the tin oxide/hydroxide phase, while the appearance of metallic Sn is suppr...

Semiconducting nanoparticle tin oxide-based sensors have been prepared with a pressure load of 4, 6, 8, 10 tons and reinforced with carbon nanofibers (CNF) in SnO2 matrix. The SnO2/CNF sensor’s sensitivity for ethyl alcohol has increased by a factor of two, in compared with that of pure SnO2 8-ton pressed sensor with lower response time. These results open the way towards further optimized lowe...