An anatase TiO(2) material with hierarchically structured spheres consisting of ultrathin nanosheets with 100% of the [001] facet exposed was employed to fabricate dye-sensitized solar cells (DSCs). Investigation of the electron transport and back reaction of the DSCs by electrochemical impedance spectroscopy showed that the spheres had a threefold lower electron recombination rate compared to ...

The dinuclear dialkoxo-bridged complexes [(TiCl)(2)(mu-O(2)L)(mu-{(eta(5)-C(5)Me(4)SiMeO)(2)(mu-O)})] (O(2)L = 1,2-O(2)C(2)H(4), 1,2-O(2)C(6)H(4), 1,2-(OCH(2))(2)C(6)H(4), O(2)SiPh(2)) were obtained by reaction of [(TiCl(2))(2)(mu-{(eta(5)-C(5)Me(4)SiMeO)(2)(mu-O)})] () with the corresponding dilithium salt () or diol (, , ). Alkylation of and with ClRMg afforded [(TiR)(2)(mu-O(2)L)(mu-{(eta(5)...

A simple procedure for SnCl(2)/TiCl(3)-mediated deoximation of ketoximes in an aqueous solvent is reported. Under the conditions developed in this effort, various ketones and aldehydes are produced in good to excellent yields.

A one-pot indole synthesis consisting of a highly regioselective TiCl(4)-catalyzed hydroamination and a 5-endo Heck cyclization starting from 2-chloroaniline is described, using an in-situ generated, sterically hindered imidazol-2-ylidene palladium complex.

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BACKGROUND To report the clinical outcomes of correcting pseudophakic ametropia using toric implantable collamer lens with a 360 um central hole (TICL V4c). CASE PRESENTATION The right eye of a 22-year-old male patient developed high myopia after unilateral phacoemulsification and intraocular lens (IOL) implantation following traumatic cataract 16 years ago. The manifest refraction was -11.50...

A titanocene-catalyzed multicomponent coupling to provide diarylethynyl methanes is described. By combining the multifunctionality of Cp(2)TiCl(2) with the traceless dielectrophilicity of aryl aldehydes, all-carbon tertiary centers are obtained in 55-99% yield.

We have developed a practical synthesis of unique nucleoside derivatives via TiCl(4) promoted multicomponent reaction of optically active dihydrofuran, ethyl pyruvate/glyoxylate, and a TMS protected nucleobase in a single-pot operation.

A novel and facile process is reported for water-phase synthesis of high-quality graphene/TiO(2) composite nanosheets (GTCN) on a large scale using TiCl(3) as both a reducing agent and a precursor.

We report a new and fast domino synthesis of aminoalcohols under mild conditions. The free-radical reaction of aliphatic and aromatic amines with alcohol cosolvents is promoted by means of the TiCl(4)-Zn/t-BuOOH system. According to the proposed mechanism, the amine reacts with two molecules of alcohol in an electrophilic-nucleophilic cascade process. This procedure, if compared with the TiCl(3...