The non-heme iron complexes, [Fe(II)(N3PySR)(CH3CN)](BF4)2 () and [Fe(II)(N3Py(amide)SR)](BF4)2 (), afford rare examples of metastable Fe(iii)-OOH and Fe(iii)-OOtBu complexes containing equatorial thioether ligands and a single H-bond donor in the second coordination sphere. These peroxo complexes were characterized by a range of spectroscopic methods and density functional theory studies. The ...

A pyridine and thioether co-supported triazole ligand L (L = 2-((4-(3-(cyclopentylthio)propyl) -1H-1,2,3-triazol-1-yl)methyl)pyridine) has been synthesized using the CuAAC click reaction. This ligand supports the formation of a thermally stable, one-dimensional coordination polymer [L2Ag4]n·4n(BF4) (1) possessing a cationic polymeric structure with [Ag4] metallomacrocycles, in which the ligand ...

Pyrazole and benzotriazole-containing thioethers, namely 1,5-bis(3,5-dimethylpyrazol-1-yl)-3-thiapentane, 1,8-bis(3,5-dimethylpyrazol-1-yl)-3,6-dithiaoctane and 1,3-bis(1,2,3-benzotriazol-1-yl)-2-thiapropane were prepared and fully characterized. Oxidation of the pyrazole-containing thioether by hydrogen peroxide proceeds selectively to provide a sulfoxide or sulfone, depending on the amount of...

Heteroleptic copper complexes containing an acetylacetonato ligand and a thioether derivatized dipyrrinato ligand are shown to form oligomers and polymers in the solid state.

Bifunctional tetrakis(methylthio)-1,4-benzenedicarboxylic acid and Pb2+ ions form a robust porous net featuring free-standing thioether groups that allow reversible uptake of HgCl2.

Adsorption characteristics of the antibiotic meropenem on a novel magnetic material synthesized by surface coating cobalt iron oxide (CFO) with gold nanoparticles (AuNPs) were systematically investigated. The AuNPs can enhance adsorption capacity having high affinity towards thioether and amine groups in structure. Au coverage CFO decreased saturation magnetization from 55.8 emu/g to 48.8 emu/g...

The rhodium-catalyzed intermolecular asymmetric hydroalkoxylation and hydrosulfenylation of diphenylphosphinylallenes gave chiral allylic phosphine oxides substituted with vinyl ether and thioether moieties in high yields with high enantioselectivities.

A series of fully bio-based poly(ester- alt -thioether)s are efficiently synthesized by organo-catalyzed alternating ring-opening copolymerizations eugenol-derived monomers, vanillin glycidyl ether and N -acetyl homocysteine thiolactone.