application of cogeneration systems based gas turbine for heat and power production is increasing. because of finite natural energy resources and increasing energy demand the cost effective design of energy systems is essential. cgam problem as a cogeneration system is considered here for analyzing. two new approaches are considered, first in thermodynamic model of gas turbine and cogeneration ...

background and objectives: lipases are valuable biocatalysts which are widely used in the detergent, food, dairy and pharmaceutical industries. the aims of the present study included the isolation of a lipase-producer from industrial zones and the partial characterization of the enzyme. materials and methods: a number of bacteria were isolated from sites related to the oil industries. an isolat...

calculate some thermodynamic properties of molten polymers including specific volume and isothermal compressibility (s.m. hoseini, physical chemistry & electrochemistry, 2 (2014) 56-65). this work extended that eos to predict the volumetric properties of some molten ethylene copolymers including ethylene/1-octene, ethylene/1-butene (xethylene equal to 0.8543 and 0.563), ethylene/propene. the ab...

in this study, aggregation behavior of a water soluble cationic metalloporphyrin, meso-tetrakis (2,3,5,6-tetrafluoro-n,n´,n´´-trimethyl ammonium phenyl) porphyrin nickel(ii) [ni(ii)(tf4tmapp)]4+ is investigated in 5 mm aqueous phosphate buffer of ph 7.0 at 25.0 °c and various ionic strengths using optical absorption and resonance light scattering spectroscopic methods. the results suggest that ...

Thermodynamic length is a metric distance between equilibrium thermodynamic states. Among other interesting properties, this metric asymptotically bounds the dissipation induced by a finite time transformation of a thermodynamic system. It is also connected to the Jensen-Shannon divergence, Fisher information, and Rao's entropy differential metric. Therefore, thermodynamic length is of central ...

the thermodynamic properties of fluids can be predicted using the global equations of state. among these thermodynamic properties of fluids, we choose the densities of the liquid and vapor phases. this paper considers the application of the crossover model to the vapor-liquid rectilinear diameter of sulfurhexafluoride. we also present a comparison of the crossover model equation with the experi...

the thermodynamic of the known and very effective catalytic system, hydrogen peroxide (h2o2) and methyltrioxorhenium (mto) is studied in different solvents using uv-visible spectroscopic method. the thermodynamic parameters (δg, δh and δs) for two equilibrium reactions, mto + h2o2 ⇌ a + h2o and a + h2o2 ⇌ b.h2o (a, [mere(o)2(o2)]; b.h2o, [mere(oh2)(o)(o2)2]), are determined. the obtained free e...

2 Thermodynamics 4 2.1 The Foundations of Thermodynamics . . . . . . . . . . . . . . . 4 2.2 Thermodynamic Equilibrium . . . . . . . . . . . . . . . . . . . . 5 2.3 The Conditions for Equilibrium . . . . . . . . . . . . . . . . . . . 7 2.4 The Equations of State . . . . . . . . . . . . . . . . . . . . . . . . 13 2.5 Thermodynamic Processes . . . . . . . . . . . . . . . . . . . . . . 14 2.6 Ther...

A new method of successive construction of a solution is developed for problems of strongly nonequilibrium Boltzmann kinetics beyond normal solutions. Firstly, the method provides dynamic equations for any manifold of distributions where one looks for an approximate solution. Secondly, it gives a successive procedure of obtaining corrections to these approximations. The method requires neither ...