Although the tartrates have been considered as possible metabolites in higher plants since the initial work of Pasteur in 1848, surprisingly little is known of their actual physiological significance. Vickery and Palmer (35) have briefly reviewed the history of (+)-tartrate in plants, including the problems of identification and of nomenclature. They conclude that (+)-tartrate is an uncommon pl...

Rochelle salt, K(+)·Na(+)·C(4)H(4)O(6) (2-)·4H(2)O, is known for its remarkable ferroelectric state between 255 and 297 K. The current investigation, based on data collected at 105 K, provides very accurate structural information for the low-temperature paraelectric form. Unlike the ferroelectric form, there is only one tartrate molecule in the asymmetric unit, and the structure displays no dis...

The Michael addition of 3-substituted oxindoles to nitroolefins was catalyzed by a novel tartrate-derived guanidine in high yield with excellent diastereo- and enantioselectivity. This method showed an extraordinarily broad substrate scope in terms of both reaction partners.