in this study chemical method of dissolution-precipitation was applied to produce amorphous silica nanoparticles from rice straw ash (rsa), the waste material of rice cultivation. the morphology, particle size, structure and area of specific surface of synthesized amorphous silica nanoparticles were evaluated using transmission electron microscopy (tem), x-ray diffraction analysis (xrd) and bet...

ammonium carbonate and ammonium sulfate have been proposed and used as two new fuels for synthesizing gamma alumina nanoparticles. the prepared samples have been characterized by x-ray diffraction (xrd), 2 n  adsorption (bet) and transmission electron microscopy (tem). a comparison has been made between the properties of the nanoparticles synthesized by these two fuels and other conventional fu...

Nanoparticles assemblies of hundreds to thousands of atoms and a size in the range of 1-50 nm can be considered at first approximation as a state of matter intermediate between single atoms or molecules and bulk bodies. While the properties of atoms and molecules can be described via quantum mechanics, the properties of bulk bodies are described by solidstate physics. Using quantum chemical mod...

Plasmonic nanoparticles are commonly used as optical transducers in sensing applications. The optical signals resulting from the interaction of analytes and plamsonic nanoparticles are influenced by surrounding physical structures where the nanoparticles are located. This paper proposes inverse opal photonic crystal hydrogel as 3D structure to improve Raman signals from plasmonic staining. By h...

zinc oxide (zno) nanoparticles were synthesized by spray pyrolysis method using an aqueous solution of zinc acetate at various concentrations from 5 to 25 wt%. the decomposition of precursor solutions was carried out at 800, 1000 and 1200ºc under different atomizing pressures. the crystal structure and morphology of synthesized nanoparticles were characterized by x-ray diffraction (xrd) spectro...

Layers of thiophenol functionalized spherical gold nanoparticles grafted on Si(100) are probed by linear UV-vis, Fourier transform infrared and nonlinear infrared-visible vibrational sum/difference–frequency generation spectroscopies as a function of the nanoparticles surface coverage. Depending on the dipping time (5 min, 20 min, 1 h, and 24 h) in the colloidal solution, AFM imaging corroborat...

this study aims at exploring an effective route in the in situ graft polymerization of aniline from fe3o4 nanoparticles. to this goal, fe3o4 magnetic nanoparticles were prepared by coprecipitation method using ammonia solution as the precipitating agent, and were characterized by fourier transform infrared (ft-ir) spectroscopy, x-ray diffraction (xrd) and transmission electron microscopy (tem)....

in the present investigation surface modification of silica nanoparticles by alumina was carried out by sol-gel process. fourier transform infrared (ftir) and x-ray fluorescence (xrf) confirmed the synthesis of silica and the surface modification as alumina is anchored to silica surface. field emission scanning electron microscopy (fesem) and transmission electron microscopy (tem) investigation...

Here we present results that investigate the origins of signals observed in tip-enhanced Raman (TERS) measurements of functionalized nanoparticles. Surface enhanced Raman scattering (SERS) is known to give the largest enhancements in gap junctions. Similarly, gap-mode TERS also produces significant enhancements. The methodology developed here provides gap-mode like enhancements in TERS measurem...

Molecular imaging agents enable the visualization of phenomena with cellular and subcellular level resolutions and therefore have enormous potential in improving disease diagnosis and therapy assessment. In this article, we describe the synthesis, characterization, and demonstration of core-shell, biofunctionalized, gadolinium-containing Prussian blue nanoparticles as multimodal molecular imagi...