The axial dispersion coefficient of hexachlorobenzene in supercritical carbon dioxide is investigated in a fixed-bed packed with glass beads. The on-line chromatographic pulse-response experiment is used in order to study the dynamics of a packed column under supercritical conditions. The radial dispersion is assumed negligible because of the packed column geometry. To estimate the axial disper...

solubility of high molecular weight n-paraffins in supercritical carbon dioxide has been a matter of interest to many researchers. however, not sufficient solubility experimental data are available although the methods by which the experimental data are obtained have many varieties. utilizing cubic equations of state is an effective method for solubility prediction of n-paraffins in supercritic...

Article history: Received October 15, 2011 Accepted 10 March 2012 Available online 12 March 2012 The recent development of world is being adversely affected by the scarcity of power and energy. To survive in the next generation, it is thus necessary to explore the non-conventional energy sources and efficiently consume the available sources. For efficient exploitation of the existing energy sou...

The demand for a new solvent to treat oilsands was behind the purpose of this project; molecular dynamics simulation was used in this study. Supercritical water, supercritical carbon dioxide and other selected organic solvents in their supercritical state were studied. Meso-tetraphenyl porphyrin (H2TPP) and Octaethyl porphyrin (H2OEP) are the porphyrin model compounds and, 4’-Bis-(2-pyren-1-yl-...

Supercritical fluids and ionic liquids offer attractive opportunities for modifying and applying zeolites as adsorbents and catalysts. After a brief introduction to the most important properties of these solvents, examples of zeolite applications in supercritical fluids and ionic liquids from the recent literature are discussed. Particular emphasis is put on the influence of reaction media on t...

Modern concepts of nuclear reactors cooled with supercritical water are presented together with a short history. The supercritical water-cooled CANDU ((CANada Deuterium Uranium) is a registered trademark of AECL) reactor concept is fully discussed. Also, thermophysical properties at critical and supercritical pressures as well as heat transfer and hydraulic resistance at these conditions are pr...

Title of Dissertation: HEAT TRANSFER AND MECHANICAL DESIGN ANALYSIS OF SUPERCRITICAL GAS COOLING PROCESS OF CO2 IN MICROCHANNELS Guohua Kuang, Doctor of Philosophy, 2006 Directed By: Professor Michael Ohadi, Department of Mechanical Engineering Professor Balakumar Balachandran (Co-Advisor), Department of Mechanical Engineering An extensive review of the literature indicates a lack of systematic...

Many advantages of supercritical fluids come from their interesting or unusual properties which liquid solvents and gas carriers do not possess. Such properties and possible applications of supercritical fluids are reviewed. As these fluids never condense at above their critical temperatures, supercritical drying is useful to prepare dry-gel. The solubility and other important parameters as a s...

In recent years, the use of supercritical fluids (SCFs) for the synthesis and processing of nanomaterials has proven to be a rapid, direct, and clean approach to develop nanomaterials and nanocomposites. The application of supercritical fluid technology can result in products (and processes) that are cleaner, less expensive, and of higher quality than those that are produced using conventional ...

Recent studies have shown that it is possible to electrodeposit a range of materials, such as Cu, Ag and Ge, from various supercritical fluids, including hydrofluorocarbons and mixtures of CO2 with suitable co-solvents. In this perspective we discuss the relatively new field of electrodeposition from supercritical fluids. The perspective focuses on some of the underlying physical chemistry and ...