A nanolayer of composite and Rhodococcus erythropolis biocatalyst was studied for the first time for desulfurization of dibenzothiophene as a model sulfur compound and its performance was compared with that of composite and R. erythropolis alone. The nanolayer of composite was synthesized by sol-gel method from ferrous oxalate and zinc oxalate precursors coated on glass by spin coating techniqu...

Manganese oxide-coated TiO2 nanotube array (NTA) was synthesized and applied for the (electro) catalytic oxidation of sulfide. By setting electrodeposition parameters calcination temperature, coating obtained MnO2 or Mn2O3, with rod needle like morphology. Excellent activity Ti/TiO2 NTA/MnxOy anodes resulted in robust selective sulfide to elemental sulfur via an inner sphere complex between ion...

Aim: Oral malodor (halitosis) is a widespread condition caused by oral bacteria, particularly sulfur compound-producing species. This study assessed the effect of a triclosan/copolymer-containing dentifrice and a novel toothbrush with attached tongue cleaner on oral malodor and on the bacteria colonizing the dorsal surface of the tongue. Materials and Methods: 14 adult subjects with oral malodo...

While sulfir in diesel fuels helps reduce friction and prevents wear and galling in fuel pump and injector systems, it also creates environmental pollution in the form of hazardous particulate and S02 emissions. The environmental concern is the driving force behind industry’s efforts to come up with new alternative approaches to this problem. One such approach is to replace sulfur in diesel fue...

Sulfur has a high specific capacity of 1673 mAh/g as lithium battery cathodes, but its rapid capacity fading due to polysulfides dissolution presents a significant challenge for practical applications. Here we report a hollow carbon nanofiber-encapsulated sulfur cathode for effective trapping of polysulfides and demonstrate experimentally high specific capacity and excellent electrochemical cyc...

Cobalt phthalocyanine (CoPc) films were deposited on the surface of a screen-printed carbon electrode using a simple drop coating method. The cyclic voltammogram of the resulting CoPc modified screen-printed electrode (CoPc/SPE) prepared under optimum conditions shows a well-behaved redox couple due to the (Co(I)/Co(II)) system. The CoPc/SPE surface demonstrates excellent electrochemical activi...

nt matter & 2013 0.1016/j.nanoen.2 thor. Tel.: +1 301 . [email protected] ( Abstract This work demonstrates the effect of atomic layer deposited (ALD) Al2O3 on the reactivation of dissolved polysulfides in Li–S batteries. A 0.5 nm thick layer of Al2O3 is conformally coated onto highly porous carbon cloth by ALD, and then assembled in a Li–S battery between the sulfur cathode and the anode side (sep...

The ductile iron liquid metal is very reactive with environmental gases and solid molds after a nodulizing treatment. Mold-metal reactions could alter the spheroidal graphite shape to vermicular or flake. In this research, the metal-mold reactions were enhanced by various sulfur additions to the no-bake mold inserts to study these phenomena and to artificially produce layered dual-graphite stru...