Co(II)-based metalloradical catalysis has, for the first time, been successfully applied for asymmetric intramolecular C–H alkylation of acceptor/acceptor-substituted diazo reagents. Through the design and synthesis of a new D2-symmetric chiral amidoporphyrin as the supporting ligand, the Co(II)-based metalloradical system, which operates at room temperature, is capable of 1,5-C–H alkylation of...

BACKGROUND Vapor–liquid and liquid–liquid equilibria of unsaturated saturated hydrocarbons with the bio-based solvent dihydrolevoglucosenone, trademarked as Cyrene, have been reported recently, aiming at utilization in extraction (LLX) extractive distillation (ED). In this work, for a model system comprised methylcyclohexane (MCH) toluene (TOL), both LLX-based ED-based processes were compared o...

Solvent is one of the important components in chemical processes. The type solvent that often used paint and coating industry a hydrocarbon-based which consists diverse complex mixture liquids contains aliphatic, alicyclic aromatic (C5-C8) elements. Aromatic hydrocarbons are environmental pollutants known to be toxic, carcinogenic mutagenic, so with an content less than 1% needed. An appropriat...

3-Azido-1-propyne oligomer (oligoAP) samples, prepared by copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) polymerization, were quarternized quantitatively with methyl iodide in sulfolane at 60 °C to obtain soluble oligomers. The conformation of the quarternized oligoAP in dilute DMSO-d 6 solution was examined by pulse-field-gradient spin-echo NMR based on the touched bead model.