UNLABELLED Indoor surfaces have a sorptive capacity for organic pollutants which may be significantly influenced by other gases and the pH of the surface. In this research, we examine the influence of a common indoor gaseous acid, CO2, and base, NH3, on the adsorption of a volatile organic base, trimethylamine (TMA), to a mineral surface, zirconium silicate beads. Varying ammonia and CO2 within...

A novel extraction approach was developed based on rotating-disk sorptive extraction (RDSE). In this approach the rotating-disk extraction device consists of a Teflon disk, with a cavity that is loaded with a commercial sorbent phase selected according to the polarity of the analyte. To avoid leakage of the sorbent, the cavity is covered with a fiberglass filter and sealed with a Teflon ring. T...

A novel, simple, and inexpensive approach to sorptive extraction, which we call solvent in silicone tube extraction (SiSTEx), was applied to pesticide residue analysis and its effectiveness and efficiency were evaluated. In SiSTEx, which is a form of open tubular sorptive extraction, a piece of silicone tubing (4 cm long, 1.47 mm ID, 1.96 mm OD in this study) is attached to the cap of a 20 mL g...

Micro extraction techniques represent the current state of the art in analytical sample preparation characterized with solvent-free/solventminimized extraction, miniaturization and automation to treat samples with pharmaceutical, food, forensic, and environmental significance for instrumental analysis. To be consistent with today’s challenges of sustainability and environmental issues, Green An...

A derivative spectrofluorimetric method for simultaneous determination of enrofloxacin (EFX) and ciprofloxacin (CFX) in cow milk was developed. The sample preparation based on rotating disk sorptive extraction (RDSE) using Oasis HLB® as phase followed by desorption the analytes with methanol. final extracts were evaluated spectrofluorimetry.

The sorption rate and metabolic fate of nitrogen dioxide, a major air pollutant, have been determined for Phaseolus vulgaris (L.). Sorption was determined kinetically by chemiluminescent monitoring of (15)NO(2) removal from the test atmosphere and directly by mass spectrometric analysis of nitrogen derived from the plant tissue. Sorptive processes were first order with respect to (15)NO(2) conc...