Abstarct: Nanostructured colloidal semiconductors with heterogeneous photocatalytic behavior have drawn considerable attention over the past few years. This is due to their large surface area, high redox potential of the photogenerated charge carriers, and selective reduction/oxidation of different classes of organic compounds. In the present paper, we have carried out a systematic synthesis of...

In this study, hydroxyapatite (denoted as HAp) nanostructure with uniform morphologies, controllable size, nano-dispersion and narrow size distribution in diameter has been synthesized successfully by low-temperature hydrothermal process, and the as-synthesized powders were characterized by XRD, scanning electron microscopy, high-resolution transmission microscopy, FT-IR, Zetasizer and inductiv...

The sonochemical decomposition of volatile organometallic compounds produces high surface area solids that consist of agglomerates of nanometer clusters. For iron pentacarbonyl and tricarbonylnitrosylcobalt, nanostructured metals and alloys are formed; for molybdenum hexacarbonyl, the metal carbide is produced. These sonochemically produced nanostructured solids are active heterogeneous catalys...

Fundamental knowledge on intrinsic plutonium colloids is important for the prediction of plutonium behaviour in the geosphere and in engineered systems. The first synthetic route to obtain salt-free intrinsic plutonium colloids by ultrasonic treatment of PuO2 suspensions in pure water is reported. Kinetics showed that both chemical and mechanical effects of ultrasound contribute to the mechanis...

Perfluorinated chemicals such as perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) are environmentally persistent and recalcitrant to most conventional chemical and microbial treatment technologies. In this paper, we show that sonolysis is able to decompose PFOS and PFOA present in groundwater beneath a landfill. However, the pseudo first-order rate constant for the sonochemica...

A new sonochemical process for the top-down production of silicon nanoparticles (<1 nm) with surface functional groups is described. The procedure involves a combination of acoustic cavitation erosion of a single-crystalline silicon surface coupled with simultaneous reaction with a reactive organic compound such as 1-hexyne. The sonochemical formation of the photoluminescent silicon nanoparticl...

The sonochemical technique has already been proven as one of the best coating methods for stable functionalization of substrates over a wide range of applications. Here, we report for the first time on the simultaneous sonochemical dyeing and coating of textiles with antibacterial metal oxide (MO) nanoparticles. In this one-step process the antibacterial nanoparticles are synthesized in situ an...

A solvent-free procedure for the synthesis of 3-substituted indole derivates from indoles and nitroalkenes under ultrasound irradiation is described. Control experiments disclosed besides mechanical effects, namely agitation, sonochemical effects are the main forces to drive the reaction. In the method, 2-chloroethanol was used to prepare a wide variety of 3-substituted indole derivates. This p...

Metal Organic Framework (MOF) is a material that serves as photocatalyst for decomposing methylene blue pollutant. MOF can be constructed using several kinds of synthetic methods. This study aims to determine the alternative efficient and eco-friendly synthesis method isonicotinic acid-modulated chromium perylene 3,4,9,10-tetracharboxylate (Cr-PTC-HIna) solvothermal, hydrothermal, sonochemical,...