in the present work, an efficient modified carbon-ceramic electrode by multi-walled carbon nanotubes/ionic liquid nanocomposite (mwcnts/il/cce) was prepared through a simple and repeatable procedure. the introduced modified electrode was used for the study of the electrochemical behaviour and determination of tryptophan (trp) in the presence of uric acid (ua) using cyclic voltammetry (cv), diff...

a new fourier transform-infra red (ft-ir) spectrometric method was developed for assaying hydrochlorothiazide (hct) and enalapril maleate (enm) in binary solid pharmaceutical formulations. multivariate partial least squares (pls) method was used for calibration of derivative spectral data. acetonitrile was used as solvent due to its spectral transparency and adequate solubility of analytes in i...

Attempts to obtain experimental values for the kinetic parameters of phenanthridine oxidation by guinea pig or rabbit liver aldehyde oxidase using common spectrophotometric methods have not been successful due to a lower limit of detection. In the present study, a new spectrofluorimetric assay in combination with a multivariate calibration method for enzymatic kinetic study of aldehyde oxidase ...

Attempts to obtain experimental values for the kinetic parameters of phenanthridine oxidation by guinea pig or rabbit liver aldehyde oxidase using common spectrophotometric methods have not been successful due to a lower limit of detection. In the present study, a new spectrofluorimetric assay in combination with a multivariate calibration method for enzymatic kinetic study of aldehyde oxidase ...

The present study describes the application of simultaneous kinetic spectrophotometric determination of hydrazine (HZ) and isoniazid (INH), using H-point standard addition method (HPSAM) and partial least squares (PLS) calibration. The methods are based on the difference observed in the rate of iron (III) reduction with HZ and INH, in the presence of 2,2'-bipyridine (Bpy) and the subsequent com...

h-point standard addition method (hpsam) with simultaneous addition of both analytes in nonaqueous solution was applied for determination of levonorgestrel (lev) and ethinyl estradiol (ee)  in ld and hd tablets. the results showed that, simultaneous determination could be performed with the ratio 1 to 5 of lev-ee. the lod for lev and ee were obtained 5.1×10 -7 and 9.6×10 -7 m, respectively, and...

a carbon ionic liquid electrode (cile) modified with tio2-fe nanoparticles was constructed by incorporating tio2-fe nanoparticles into the paste matrix. under the optimized experimental conditions, using differential pulse voltammetry (dpv), the oxidation of thiocyanate and oxalate were occurred at potentials of 0.740 v and 1.010 v, respectively, at the surface of the modified electrode. observi...

kinetic modeling is an important issue, whose objective is the accurate determination of the rates of various reactions taking place in a reacting system. this issue is a pivotal element in the process design and development particularly for novel processes which are based on reactions taking place between various types of species. the fischer tropsch (ft) reactions have been used as the kineti...