DNA-stabilized silver clusters are remarkable for the selection of fluorescence color by the sequence of the stabilizing DNA oligomer. Yet despite a growing number of applications that exploit this property, no large-scale studies have probed origins of cluster color or whether certain colors occur more frequently than others. Here we employ a set of 684 randomly chosen 10-base oligomers to add...

We have calculated the absorption characteristics of different hybrid systems consisting of Ag, Ag(2), or Ag(3) atomic clusters and poly(methacrylic acid) using the time-dependent density-functional theory. The polymer is found to have an extensive structural-dependency on the spectral patterns of the hybrid systems relative to the bare clusters. The absorption spectrum can be "tuned" to the vi...

Luminescent silver nanoclusters were anchored by designed oligonucleotides. After hybridizing with human telomerase RNA template, the luminescence of the cluster decreased linearly with respect to the concentration of the complementary strand (25-250 nM). The cluster is therefore a potential candidate for human telomerase detection.

A dual-templated approach for the controllable synthesis of metal cluster complexes is described. By using an acetylide-containing anion with specific geometry as a central template and a macrocyclic coordinative compound as a peripheral one, two multinuclear silver-acetylide cluster-encapsulated supramolecular boxes were synthesized.

Molecular quantum clusters of noble metals are a fascinating area of contemporary interest in nanomaterials. While Au11, [1] Au13, [2] and Au55 [3] have been known for a few decades, several new clusters were discovered recently. These include Au8, [4] Au18, [5] Au25, [6] Au38, [7] and so on. Au11 has also been the subject of recent research. In view of their luminescence, several of these clus...

Cluster-assembled nanostructured carbon with a fractal morphology is employed as a large-area surface scaffold for metal decoration. By depositing silver by pulsed laser ablation densely packed, distributions of metal nanoparticles are produced. The authors show, using the surface-enhanced Raman effect and the modification of fluorescence quantum yields near metallic surfaces, that silver-coate...

We report a one-step and high yield synthesis of a redluminescent silver cluster with the molecular formula, Ag11(SG)7 (SG: glutathionate) via reduction of silver ions by sodium borohydride in the presence of the tripeptide, glutathione (GSH). The as-prepared cluster shows prominent absorption features at 485 and 625 nm in its UV−vis absorption spectrum. Aging of the as-prepared cluster solutio...

Panchromatic Luminescent Silver Nanodots In article number 2201121, Junhua Yu and colleagues show that panchromatic luminescent silver nanodots can be generated by cluster transference in a single step, with excellent spectral purity chemical stability. This strategy utilized fields such as imaging several targets after turn-on step; it also used for fast efficiently visualizing printed micropa...