A series of Fe3O4 supported on mesoporous FDU-12 silica systems were prepared by the hydrothermal conditions. The surface properties of the functionalized catalyst were analyzed by a series of characterization techniques like FTIR, XRD, N2 adsorption–desorption and TEM. XRD and adsorption–desorption analysis shows that the mesostructure of FDU silica remains intact after Fe3O4 modifications, wh...

silica ferric hydrogensulfate is an efficient heterogeneous catalyst for the cyclization of 2- aminochalcones to the corresponding 2,3-dihydroquinolin- 4(1h)-ones. this intramolecular aza michael reaction was carried out in high yields using chalcones bearing of electron donating and electron withdrawing groups. the catalyst is reusable without significant decreases in its activity after four t...

Deprotection of various phenols from their respective methoxymethyl ethers using an heteropolyacid catalyst was studied. The catalyst was the Wells-Dawson heteropolyacid, used both in bulk or supported on silica. Yields were high to quantitative after less than one hour reaction time and the catalyst was easily recoverable and reusable.

A series of Fe3O4 supported on mesoporous FDU-12 silica systems were prepared by the hydrothermal conditions. The surface properties of the functionalized catalyst were analyzed by a series of characterization techniques like FTIR, XRD, N2 adsorption–desorption and TEM. XRD and adsorption–desorption analysis shows that the mesostructure of FDU silica remains intact after Fe3O4 modifications, wh...

Silica ferric hydrogensulfate is an efficient heterogeneous catalyst for the cyclization of 2- aminochalcones to the corresponding 2,3-dihydroquinolin- 4(1H)-ones. This intramolecular aza Michael reaction was carried out in high yields using chalcones bearing of electron donating and electron withdrawing groups. The catalyst is reusable without significant decreases in its activity after four t...

Supported olefin polymerization catalysts can prevent reactor-fouling problems and produce uniform polymer particles. Constrained geometry complexes (CGCs) have less sterically hindered active sites than bis-cyclopentadienyl metallocene catalysts. In the literature, micrometer-sized silica particles were used for supporting CGC catalysts, which might have strong mass transfer limitations. This ...

A green, efficient and selective approach for the oxidation of sulfides to sulfoxides and sulfones with UHP at room temperature is reported. The reaction is performed in the presence of vanadia catalyst supported on mesocellular silica foam (MCF) with a V content ranging from 2% to 10% as heterogeneous and reusable catalyst. The structural and textural characterization of this catalyst were don...

Silica ferric hydrogensulfate is an efficient heterogeneous catalyst for the cyclization of 2- aminochalcones to the corresponding 2,3-dihydroquinolin- 4(1H)-ones. This intramolecular aza Michael reaction was carried out in high yields using chalcones bearing of electron donating and electron withdrawing groups. The catalyst is reusable without significant decreases in its activity after four t...

An efficient protocol for the synthesis of 3,4-dihydropyrimidin-2-(1H)-one/thione derivatives via multi-component coupling reaction of aromatic aldehydes, β-ketoester and urea or thiourea under solvent-free conditions using Silica Supported Barium Chloride as a catalyst is described. All prepared compounds with melting points, IR,1H NMR and 13C NMR were identified. High yields, mild conditi...

A simplistic green and neat procedure was developed for the synthesis of arylmethyl and heteroaryl phosphonates or phosphinates by silica gel supported Lewis acid catalyst, CeCl3.7H2O-SiO2 through Michaelis-Arbuzov reaction under conventional as well as microwave irradiation methods. Herein, tetraalkyl 1,4phenylenebis(methylene)diphosphonates 5(a-d)/dimethyl 1,4-phenylenebis(methylene)bis (phen...