نتایج جستجو برای: sba 15 عاملدار شده

تعداد نتایج: 935689  

2010
YL Xue P Wu Y Liu X Zhang L Lin Q Jiang

SiO(2) mesoporous molecular sieve SBA-15 with the incorporation of erbium ions is studied as a novel type of nanoscopic composite photoluminescent material in this paper. To enhance the photoluminescence efficiency, two schemes have been used for the incorporation of Er(3+) where (1) Er(3+) is ligated with bis-(perfluoromethylsulfonyl)-aminate (PMS) forming Er(PMS)(x)-SBA-15 and (2) Yb(3+) is c...

Journal: :Chemical communications 2005
Richard L Brutchey Ian J Drake Alexis T Bell T Don Tilley

A new pseudo-tetrahedral Co(II) complex has been grafted onto the surface of SBA-15 and successfully utilized for the catalytic oxidization of alkylaromatic substrates with tert-butyl hydroperoxide (TBHP)via an H-atom transfer mechanism.

2010
Huayu Huang Yongsheng Ji Zhenfeng Qiao Chuande Zhao Jianguo He Haixia Zhang

Magnetic Fe-SBA-15 mesoporous silica molecular sieves were prepared, characterized, and used for magnetic separation. Wet impregnation, drying, and calcination steps led to iron inclusion within the mesopores. Iron oxide was reduced to the metal form with hydrogen, and the magnetic Fe-SBA-15 was obtained. Fourier-transform infrared spectroscopy confirmed the preparation process from the oxide t...

Journal: :Langmuir : the ACS journal of surfaces and colloids 2006
Huan Wang Frank L Y Lam Xijun Hu Ka Ming Ng

An ordered mesoporous carbon, CMK-3, was synthesized using a mesoporous siliceous material, SBA-15, as the template. CMK-3 was characterized and used for the adsorption of fullerenes C60 and C70. It was found that the adsorption capacity of CMK-3 is 4 times higher than that of activated carbon. The adsorption equilibrium isotherms of C60 and C70 on CMK-3 were studied for both single and binary ...

Journal: :Nanoscale 2012
Min Xue Dennis Cao J Fraser Stoddart Jeffrey I Zink

pH-responsive megagates have been fabricated around mesoporous silica material SBA-15 in order to mechanize the mesopores. These megagates remain closed in neutral conditions, but open at pH 5. The capping components of the megagates were designed to be capable of controlling pores up to 6.5 nm in diameter. Selectivity of payloads with different sizes can be achieved through the use of differen...

1980
Rahmat Ahmad Zuhairi Abdullah Abdul Rahman Mohamed

Problem statement: Santa Barbara Amorphous (SBA-15) is significant mesoporous silica with exclusive and important properties of highly ordered mesopores, hydrothermally stable and thick wall, profusely large surface area and huge pore volume which render it as promising catalyst for wide applications. However, the purely siliceous SBA-15 which lacks of acidity characteristic hinders its ideal c...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه صنعتی اصفهان - دانشکده عمران و محیط زیست 1391

آلودگی اکوسیستم های آبی به رنگ ها یکی از اصلی ترین معضلات زیست محیطی قرن حاضر است که نیازمند ارائه راه حل های فوری و موثر در جهت حذف این آلاینده ها می باشد. بسیاری از صنایع مانند رنگرزی، نساجی، کاغذ و پلاستیک از رنگ ها و حجم زیادی آب برای رنگ کردن محصولات خود استفاده می کنند. بدین ترتیب مقدار زیادی پساب حاوی رنگ تولید می شود. بسیاری از آنها سمی و سرطان زا هستند و وجود آنها برای ادامه حیات آبزیا...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه صنعتی اصفهان - دانشکده مهندسی شیمی 1394

برای بررسی توانایی tio2 در تخریب ساختار فنل از ماده فعال سطحی پلورونیک پی-123، پلورونیک اف-127 و سی تب استفاده شد. همچنین کاتالیست نوری m-tio2 ساخته و اثر آن بر تخریب ساختار فنل در آب بررسی شد. در قسمت دیگر از پایه sba-15 استفاده و کاتالیست ti-sba-15 ساخته و اثر آن بر تخریب فنل بررسی شد.

Journal: :Chemical communications 2012
Guofu Zhang Yong Wang Xin Wen Chengrong Ding Ying Li

A novel SBA-15 supported catalyst PdL(n)@SBA-15 containing a 2-pyridyl-1,2,3-triazole ligand framework was prepared via a "click" route, in which the click-triazole acted as both a stable linker and a good chelator. The catalyst was characterized and applied for the aerobic oxidation of alcohols, and the product was obtained in up to 98% yield.

2014
Mehdi Esmaeili Bidhendi Gholam Reza Nabi Bidhendi Nasser Mehrdadi Hamid Rashedi

BACKGROUND Removal of mercury from aqueous environment has been highly regarded in recent years and different methods have been tested for this purpose. One of the most effective ways for mercury ions (Hg(+2)) removal is the use of modified nano porous compounds. Hence, in this work a new physical modification of mesoporous silica (SBA-15) with 1, 3, 5 (Trithiane) as modifier ligand and its app...

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