Carbon dioxide is known as a hazardous material with acidic property that can be found as impurity in natural gas reservoirs with a broad range of 2 up to 40 %. Therefore, many efforts have been directed to remove and separate carbon dioxide from methane to prevent corrosion problems as well as improving the natural gas energy content. In this study, two molecular sieves, silicoaluminophosphate...

The utilization of metal oxide-zeolite catalysts in the syngas-to-olefin reaction is a promising strategy for producing C2–C4 olefins from non-petroleum resources. However, effect crystal phase oxides on catalytic activity these still ambiguous. Herein, typical (ZnO/ZrO2) with different phases (monoclinic (m-ZrO2) and tetragonal (t-ZrO2)) were employed syngas conversion. (ZnO/m-ZrO2+SAPO-34) co...

A detailed investigation of the hydrothermal crystallization SAPO-34 in presence novel 1-propylpyridinium hydroxide ([PrPy]OH) organic structural directing agent is presented. The synthesis conditions are systematically tuned to investigate effects various parameters (viz. concentrations each reactant, time, and temperature) on nucleation SAPO-34. results show that a careful variation formation...

The product distribution of methanol to hydrocarbons conversion over SAPO-34 and ZSM-5 catalysts was studied using thermodynamic equilibrium and Anderson-Schulz-Flory (ASF) distributions. The equilibrium compositions were calculated using constrained Gibbs free energy minimization. The effect of catalyst type was considered by setting upper limits to product carbon number due to sh...

Efficient and one-pot conversion of biomass-derived carbohydrate into highly value-added 5-hydroxymethylfurfural (HMF) is a crucial reaction step for the valorization biomass resources toward bio-based chemicals fuels. In this work, series Sn/SAPO-34 catalysts were prepared through impregnation evaluated in glucose to HMF. The physicochemical properties systematically characterized by SEM, XRD,...