in this study, the stability of trinitroglycerin (tng) in polyethylene (peg) 400 was investigated according to arrhenius approach. the reaction rate constant (k) for the thermal disintegration of tng in peg 400 at various temperatures was counted based on the percents of remaining tng at different intervals of time at a specific temperature. the results showed that “k” at 40, 50, 60, 70, 80 and...

As a sustainable alternative for conventional batch-based synthetic techniques, the concept of continuous-flow processing has emerged in the synthesis of fine chemicals. Systematic tuning of the residence time, a key parameter of continuous-reaction technology, can govern the outcome of a chemical reaction by determining the reaction rate and the conversion and by influencing the product select...

A theoretical model of a surface electrode reaction coupled with a preceding chemical reaction (surface CE electrode mechanism) is theoretically studied under conditions of square-wave voltammetry. The position and the shape of the theoretical voltammograms are function of the redox kinetic parameter k 1⁄4 ks f where ks is the standard electron exchange rate constant and f is the frequency of t...

This article presents the heat and mass transfer characteristics of unsteady MHD flow of a viscous, incompressible and electrically conducting micropolar fluid in the presence of viscous dissipation and radiation over a porous stretching sheet with chemical reaction. The governing partial differential equations (PDEs) are reduced to ordinary differential equations (ODEs) by applying suitable si...

Heterogeneous catalytic hydrogenation of cyclohexene, catalyzed by Pt/A1203, was carried out in thirteenvarious solvents (four alcoholic solvents, six aprotic polar solvents and three non polar solvents) at 25 °C.Single-parameter correlations of logk vs. normalized polarity parameter (ETN), hydrogen-bond acceptorbasicity (p), hydrogen-bond donor acidity (a) and dipolarity/polarizibility (it*) d...