in the present study, advanced oxidation treatment, uv/ was applied to decolourisation of acid orange 8 (ao8). the uv radiation was carried out with a 15 w low-pressure mercury lamp. kinetic model for the decolourisation of the dye was developed based on experimental results and known chemical and photochemical reactions. the observed kinetic reaction constant was determined and correlated as a...

In this study, decolorization of the diazo dye, Reactive Black 5 (RB5) in a Coprinus cinereus peroxidase-catalyzed reaction has been investigated. A bisubstate kinetic model for the reaction rate based on the Ping-Pong mechanism was assumed for the enzymatic decolorization. Experiment...

kinetic parameters of the ammonolysis reaction of dichloroethane in nonaqueous media are studied and the optimum reaction conditions are reported. a suitable reactor for running the reaction under high pressure in the range of 50 to 500 °c is designed. kinetic behaviours of the system is studied and other reaction parameters such as rate constant, kinetic order, and activation energy are determ...

a study of the kinetic analysis of total lead from spent car battery ash by hydrochloric acidleaching has been examined. the physico-chemical analysis of the ash powder was carried outby the inductively coupled plasma-mass spectrometry (icp-ms) and x–ray diffraction (xrd).the effects of the acid concentration, temperature and particle size on the rate of battery ashdissolution have been investi...

the olefins polymerization process in a slurry reactor is discussed. the reaction rate dynamics was analyzed and the contributions of feed flow, gas-liquid mass transfer, polymerization reaction, and catalyst deactivation were estimated. the propylene solubility in a solvent mixture “heptane” was calculated using soave-redlich-kwong equation of state. these data were then approximated by henry-...

for large and complex reacting systems, computational efficiency becomes a critical issue in process simulation, optimization and model-based control. mechanism simplification is often a necessity to improve computational speed. we present a novel approach to simplification of reaction networks that formulates the model reduction problem as an optimization problem and solves it using genetic al...

mercaptans are commonly present in petroleum products. their foul odor and highly corrosive nature make them the most undesirable sulfur compounds so they should be removed because of environmental issues. merox process is used for oxidation of mercaptans to disulfide using air in the presence of alkaline solution and merox catalyst. in this paper, due to lack of information about the kinetic o...

A kinetic model of a fixed bed tubular reactor incorporating catalyst deactivation was developed for the ISOMAX unit of Arak refinery. The kinetic parameters for the hydrocracking reactions over the commercial catalyst were determined using initial activity plant data i.e. when the catalyst is fresh. Catalyst deactivation was then taken into account by means of deactivation function based on pl...

Oxidation of Methyl Orange (MO) solution in potassium peroxydisulfate (KPS) homogeneous reaction system without UV irradiation was investigated. The result shows that decolorization of MO increases as the dosage of K2S2O8 increases. The kinetic results demonstrate that the decolorization reaction is a pseudo first-order reaction when the concentration of MO ...