Due to their non-destructive character, X-ray analytical methods are widespread in the field of archaeometry. In the present study, the use of synchrotron radiation induced X-ray fluorescence analysis (SR-XRF) is illustrated on three examples: a silver point drawing of Jan van Eyck, the Hiddensee Gold Treasure, and the Sky Disc of Nebra. The possibility to analyse large objects in normal atmosp...

Lead exposure is widespread among industrial populations in the United States. X-ray fluorescence (XRF) analysis of the lead content of bone offers a promising approach to acquisition of individualized data on chronic lead absorption in occupationally exposed populations. Dosimetric data obtained by XRF will permit accurate definition of dose-response relationships for such chronic consequences...

The term 'X-ray fluorescence analysis' (XRF) refers to the measurement of characteristic fluorescent emission resulting from the deexcitation of inner shell vacancies produced in the sample by means of a suitable source of radiation. For a particular energy (wavelength) of fluorescent light emitted by a sample, the number of photons per unit time (generally referred to as peak intensity or coun...

The technique of (109)Cd-based X-ray fluorescence (XRF) measurements of lead in bone is well established. A paper by some XRF researchers [Gordon CL, et al. The Reproducibility of (109)Cd-based X-ray Fluorescence Measurements of Bone Lead. Environ Health Perspect 102:690-694 (1994)] presented the currently practiced method for calculating the variance of an in vivo measurement once a calibratio...

One of the advantages of X-ray fluorescence XRF analysis is its ability to perform accurate quantitative analysis over a wide range of elements with relative ease. In addition, its high sensitivity makes it ideal for trace elemental analysis. The establishment of analytical conditions for XRF is straightforward, including the determination of spectral line overlap correction factors. As with mo...

Strong characteristic Kα X-ray lines are accompanied by weak lines due to the radiative Auger effect (RAE) [1, 2]. The characteristic Kα fluorescent X-rays (K-L2,3 lines) are emitted by the 2p→1s electric dipole transition after one of the 1s electron photoionization, Though the probability is less than 0.01, one of the 2p electrons is excited into an unoccupied discrete or continuum level simu...

Since several years pnCCDs are well known as radiation detectors for spectroscopic imaging in many fields of science: X-Ray Fluorescence analysis (XRF), X-ray astronomy, X-ray Free Electron Laser science, synchrotrons and in the visible range as wave front sensors in adaptive optics systems. For direct electron detection in the focal plane of (S)TEMs they have delivered remarkable results in an...

X-ray fluorescence (XRF), a rapid, noninvasive, low-radiation-dose method of measuring bone lead content, has emerged as a promising tool for providing an integrated estimate of low-level lead accumulation in epidemiological studies. Our group has settled on an XRF instrument that utilizes K X-rays (K-XRF) and normalizes the measurement to bone calcium. The unit of measurement provided is in mi...

Thirteen arsenous acid samples of known origins and refining methods were collected. Each sample was subjected to quantitative analysis of any impurity elements present using synchrotron radiation X-ray fluorescence spectrometry (SR-XRF) and inductively coupled plasma-atomic emission spectrometry (ICP-AES). The trace elements selected were Sn, Sb and Bi for the reasons that they were considered...

PURPOSE Developing an imaging method to directly monitor the spatial distribution of platinum-based (Pt) drugs at the tumor region is of critical importance for early assessment of treatment efficacy and personalized treatment. In this study, the authors investigated the feasibility of imaging platinum (Pt)-based drug distribution using x-ray fluorescence (XRF, a.k.a. characteristic x ray) CT (...