A selective off-line preconcentration technique for the V(V) complex with 4-(2-pyridylazo)resorcinol has been developed and successfully applied to the determination of V(V) in an air-borne sample. The target complex was separated from excess reagent using an ODS cartridge and water as the eluent. The complex was then concentrated on another ODS cartridge using tetrabutylammonium bromide and el...

Solid-phase spectrophotometry has been applied to analysis for trace amounts of vanadium. Vanadium was sorbed in a styrene-divinylbenzene-type anion-exchanger Dowex 1-X8 as a vanadium-4-(2-pyridylazo)resorcinol complex. Resin phase absorbances at 562 and 800 nm were measured directly which allowed the determination of vanadium in the range of 0.1-2.4 ng/ml with a RSD of 1.5%. The method has bee...

Abstract In this work, we synthesized and characterized an azo dye of amino pyridine namely 6-[3- pyridylazo]-2,4-dichlorophenol (PADCP) furthermore its complexes cobalt, nickel copper divalent ions. The infrared spectra refereed that PADCP ligand coordinates by oxygen nitrogen atoms to the metals in as bidentate ligand. have general formula [M(PADCP) 2 ] which confirmed elemental analysis, mag...

The constants of the extraction equilibrium and the distribution for dichloromethane as an organic solvent having low dielectric constant of metal cations with chiral Schiff bases, benzaldehydene-(S)-2-amino-3-phenylpropanol (I), ohydroxybenzaldehydene-(S)-2-amino-3-phenyl-propanol (II), benzaldehydene-(S)-2amino-3-methylbutanol (III) with anionic dyes [4-(2-pyridylazo)-resorcinol mono sodium m...

A simultaneous injection effective mixing flow analysis (SIEMA) system was proposed for the spectrophotometric determination of palladium. The determination of palladium was based on its complexation reaction with 2-(5-bromo-2-pyridylazo)-5-[N-n-propyl-N-(3-sulfopropyl)amino]aniline (5-Br-PSAA) to form a blue complex, which has an absorption maximum at 612 nm. The analytical performances of the...