A new type of ether-bonded packing for reversed-phase HPLC (RP-HPLC) was synthesized by reacting 1-octanol with beta-(3,4-epoxycyclohexyl)ethyltrimethoxysilane, followed by coupling the product onto porous silica. The prepared packing was characterized by elemental analysis, solid-state 13C NMR, and Fourier transform infrared (FT-IR) spectroscopy. Chromatographic evaluations were performed by u...

Highly porous nanostructures with large surface areas are typically employed for electrical double-layer capacitors to improve gravimetric energy storage capacity; however, high surface area carbon-based electrodes result in poor volumetric capacitance because of the low packing density of porous materials. Here, we demonstrate ultrahigh volumetric capacitance of 521 F cm(-3) in aqueous electro...

1.1 Abstract Poromechanics offers a consistent theoretical framework for describing the mechanical response of porous solids. When dealing with fully saturated nanoporous materials, which exhibit pores of the nanometer size, additional effects due to adsorption and confinement of the fluid molecules in the smallest pores must be accounted for. From the mechanical point of view, these phenomena ...

An enzyme glucose microsensor using a glucose oxidase-immobilized porous carbon/Teflon composite microelectrode was developed. The microsensor was fabricated by etching a platinum microelectrode (platinum, radius of 25 and 50 micrometers) in hot aqua regia to create a cavity at the tip and then packing a porous carbon/Teflon composite, which was made from acetylene black and Teflon emulsion, in...

Recently we proposed a periodic surface model to assist geometric construction in computer-aided nano-design. This implicit surface model helps create super-porous nano structures parametrically and support crystal packing. In this paper, we study construction methods of Minkowski sums for periodic surfaces. A numerical approximation approach based on the Chebyshev polynomials is developed and ...

The emitted current as a function of applied voltage has been investigated for linear electrospray emitter arrays of different emitter separation distances. The emitter arrays were fabricated out of porous tungsten using conventional micro fabrication techniques adapted for use on porous substrates. Experimental results are provided for samples of each emitter density and show that the emitter ...

In this paper, the effects of container size on the porosity of random loose packing of mono size particles have been investigated using an Event Dynamics (ED) based model. Simultaneous effects of square container walls on particles packing and their order are also investigated. Our simulation results indicate higher container size will increase the total packing factor and high density regions...

Type of packings and characteristics of their geometry can affect the flow behavior in the reactive distillation columns. KATAPAK SP is one the newest modular catalytic structured packings (MCSP) that has been used in the reactive distillation columns, recently. However, there is not any study on the hydrodynamics of this packing by using computational fluid dynamics. In the present work, a 3D ...