high solid content poly (styrene-co-butyl acrylate) latex ( with 20% and 40% solid content) including high amounts of cloisite 30b (7 wt% and 10 wt%) were kinetically investigated. gravimetric method via measuring the rate of polymerization, number of particles and average number of radicals per particle was used. results showed that by increasing the solid content; the average diameter of poly...

Radiation-induced polymerization of vinylbenzyltrimethylammonium chloride (VBT) in aqueous solution has been investigated by steady-state and pulse radiolysis techniques. The effects of dose, dose rate, monomer concentration, pH, and ambient conditions on steady state polymerization were investigated. The reactions of primary radicals of water radiolysis, such as OH radical, e(-)aq, and H atom,...

We demonstrate a novel patterning technique of conductive polymers produced by vapor phase polymerization. The method involves exposing an oxidant film to UV light which changes the local chemical environment of the oxidant and subsequently the polymerization kinetics. This procedure is used to control the conductivity in the conjugated polymer poly(3,4ethylenedioxythiophene):tosylate (PEDOT:To...

The compositional dependence of the polymerization kinetics of multiacrylate copolymers with acrylic acid (AA) was examined. The multiacrylates considered were dior triacrylate esters of oligo(ethylene glycol) (OEG). The multiacrylate polymerization rate increased with the OEG chain length in the absence of added AA. This monomer size dependence was due to mobility-related effects on the pendan...

OBJECTIVES Photopolymerized composites are used in a broad range of applications with their performance largely directed by reaction kinetics and contraction accompanying polymerization. The present study was to demonstrate an instrument capable of simultaneously collecting multiple kinetics parameters for a wide range of photopolymerizable systems: degree of conversion (DC), reaction exotherm,...

graft polymerization of acrylic acid (aa) and ethyl methacrylate (ema) onto starch (st) were carried out in aqueous solution using ceric ammonium nitrate (can) as redox system under n2 atmosphere. the effect of ph, reaction time, temperature, concentrations of can, st, and monomers on the graft yield was investigated. monomer reactivity was in the following order: aa>ema.the kinetics of the gra...

In this study, slurry polymerization kinetics of ethylene with TiCl4/Mg(OEt)2/AlR3 Ziegler-Natta catalysts in various conditions using the model of sum square error (SSE) (method I) and model of least square error (LSE) (Method II) was investigated. For this purpose the molecular weight distributions of the samples were deconvoluted to the minimum number of Flor...

This article reports that the kinetics of surface-initiated atom transfer radical polymerization can be quantified by the quartz crystal microbalance with dissipation (QCM-D) technique. The kinetics of in situ growth of poly(oligoethylene glycol methylmethacrylate) monitored on a gold-coated QCM-D sensor chip revealed that changes in the experimentally observed frequency (DeltaF) and dissipatio...