The production of open-cell (OC) nanostructures in polymer foams without non-foamed solid skins by gas dissolution foaming has been developed this work. First, several grades MAM block copolymer (methyl methacrylate-b-butyl acrylate-b-methyl methacrylate) at high content are employed as heterogeneous phase poly(methyl for producing OC structures. Atomic force microscopy and extensional rheology...

Transparent and heat-resistant poly(methyl methacrylate) copolymers were synthesized by bulk polymerizing methyl methacrylate (MMA), isobornyl methacrylate (IBMA), and methacrylamide (MAA) monomers. Copolymerization was performed using a chain transfer agent to investigate the molecular weight changes of these copolymers, which exhibited advantages including a low molecular weight distribution,...

We present a straightforward low cost liquid phase deposition method to coat arbitrary-shaped dielectric substrates with uniform electron beam sensitive polymer films. Furthermore, we investigate the use of electron beam lithography to pattern the coated pre-form substrates. The polymers studied are poly-methyl-methacrylate with different molecular weights, poly(methyl methacrylate-co-ethyl acr...

We compare the efficacies of three preparation methods intended to create in an easy and inexpensive way a nonpreferential surface for a two-component homopolymer blend of polystyrene and poly(methyl methacrylate). The first method is to physically absorb two different high molecular weight copolymers of styrene and methyl methacrylate onto hydroxylated silicon oxide. The second method consists...

The in situ ATRP (atom transfer radical polymerization) "grafting from" approach was successfully applied to graft poly(methyl methacrylate) (PMMA) onto the convex surfaces of multiwalled carbon nanotubes (MWNT). The thickness of the coated polymer layers can be conveniently controlled by the feed ratio of MMA to preliminarily functionalized MWNT (MWNT-Br). The resulting MWNT-based polymer brus...

In this study, synthesis of unsaturated Poly(2-Butene Maleate) polyester by condensation polymerization and preparation cross-linked graft copolymer with methyl methacrylate are presented. For purpose, polyesters were synthesized in four different time periods (12h, 24h, 36h, 48h) the presence hydroquinone using 1,4-Butanediol-2-ene maleic anhydride. Then, obtained was purified on alumina colum...

The role of cobalt(II) complexes containing 2-formylpyrrolyl chelating ligands and phosphine ligands combined with a bromo-alkyl ester, an alkyl bromide or an azo compound in the formation of suitable initiator systems for vinyl monomer controlled radical polymerization was studied. The formation of syndiotactic-rich (Pr>0.7) poly(methyl methacrylate) (PMMA) and atactic (Pr=0.49) poly(styrene) ...