نتایج جستجو برای: polarography
تعداد نتایج: 769 فیلتر نتایج به سال:
Developments in chromato-polarography and the results obtained from its application to the analysis of mixtures of organic compounds are presented. The possibility of determining traces of organic impurities in organic substances by this technique is evaluated. The polarographic method is today one of the most important instrumental methods and has found wide application in analytical chemistry...
Helix-coil transition of poly aspartic acid (PASP) was investigated by dc polarography in the presence of Cd2+ and/or Zn2+ as a detecting marker which attached to the polymer. The diffusion currents (id) of Cd2+ and Zn2+ decreased sharply in the pH range of 3.5-7.0 due to the formation of the metal ions-PASP macromolecular complexes. The complex formation revealed on an increase in the magnitud...
A novel analytical reagent, 4-(2-hydroxyphenylethamino)benzene-1,3-diol was synthesized for determination of nickel(II) in biological samples and plant materials by extractive differential pulse polarography. The analysis of nickel(II) was carried out by extracting the nickel(II)-(4-(2-hydroxyphenylethamino)benzene-1,3-diol) complex from chloroform prior to injecting into the instrument. The el...
in present study we determine the zinc and lead levels in human blood samples by differential pulse polarography under optimum experimental conditions (ph=7.5, scan rate=5mv/s and pulse amplitude=50mv) the polarographic reduction peaks of zn and pb were examinedin the -0.72 v and-0.15 respectively. the zinc and lead content can be determined by in comparison with their standard solutions. accor...
In recent years, a series of thiamine derivatives has been synthesized and many investigations have been made both chemically and medically. Allithiamine, a S-alkyl thiamine derivative, was studied in the previous pa per (1) and was found to have polarographically a similar behavior to thia mine. In the present experiment, polarographic investigations on diacetyl thiamine (DAT) and dibenzoylthi...
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