In this work, the results relating to the mean activity coefficient measurements for ionic liquid of 1- propyl -3 methylimidazolium bromide, [PMIm]Br in ethanol+ water mixtures have been reported using potentiometric measurements at T=( 298.2, 308.2 and 318.2)K. The electromotive force (emf) measurements were performed on the galvanic cell of the type:Br-ISE│[PrMIm] (m) ethanol (wt.%), H2O (1−w...

In this study, the Langmuir adsorption isotherm has been coupled with activity coefficient models for prediction of surface tension of single and mixed electrolyte solutions. Various activity models such as Meissner, Pitzer and extended UNIQUAC have been used and coupled with Langmuir adsorption isotherm. The model parameters were determined through mathematical optimization using experimental ...

Hot potassium carbonate (PC) solution in comparison with amine solution had a decreased energy of regeneration and a high chemical solubility of . To present vapor and liquid equation (VLE) of this system and predict  solubility, the ion specific non-electrolyte Wilson-NRF local composition model (isNWN) was used in this study; the framework of this model was molecular. Therefore, it was suitab...

Introduction: The Mars Exploration Rover (MER) missions have stimulated considerable thinking about the surficial geochemical evolution of Mars [1-4]. Among the major MER findings is the presence of the mineral, jarosite (a ferric sulfate salt), which suggests formation from an acid-sulfate brine. The objectives of this work were to (1) add ferric iron chemistry to an existing ferrous iron mode...

in this study, artificial neural network was used to predict the surface tension of 20 hydrocarbon mixtures. experimental data was divided into two parts (70% for training and 30% for testing). optimal configuration of the network was obtained with minimization of prediction error on testing data. the accuracy of our proposed model was compared with four well-known empirical equations. the arti...

A model for the solubility of methane in brines (O-6 m) for temperatures from 0 to 250°C and for pressures from 0 to 1600 bar (or slightly above) is presented. The model is based on Pitzer phenomenology for the liquid phase and a highly accurate equation of state recently developed for the vapor phase. Comparison of model predictions with experimental data indicates that they are within experim...

In this work, the adsorption behavior of Sr onto a synthetic iron(III) oxide (hematite with traces goethite) has been studied. This solid, which might be considered representative Fe3+ solid phases (iron corrosion products), was characterized by X-Ray Diffraction (XRD) and Photoelectron Spectroscopy (XPS), its specific surface area determined. Both XRD XPS data are consistent mixed containing m...

A comprehensive mixed-solvent electrolyte model has been applied to calculate phase equilibria and other thermodynamic properties of multicomponent solutions containing salts, acids and bases in wide concentration ranges. The model combines an excess Gibbs energy model with detailed speciation calculations. The excess Gibbs energy model consists of a long-range interaction contribution represen...