The emulsifying ability of OSA-modified and native starch in the granular form, in the dissolved state and a combination of both was compared. This study aims to understand mixed systems of particles and dissolved starch with respect to what species dominates at droplet interfaces and how stability is affected by addition of one of the species to already formed emulsions. It was possible to cre...

HYPOTHESIS Particle bridges form in Pickering emulsions when the oil-water interfacial area generated by an applied shear is greater than that which can be stabilised by the available particles and the particles have a slight preference for the continuous phase. They can subsequently be broken by low shear or by modifying the particle wettability. EXPERIMENTS We have developed a model oil-in-...

Unmodified Fe(3)O(4) nanoparticles do not stabilize Pickering emulsions of a polar oil like butyl butyrate. In order to obtain stable emulsions, the Fe(3)O(4) nanoparticles were modified by either carboxylic acid (RCOOH) or silane coupling agents (RSi(OC(2)H(5))(3)) to increase their hydrophobicity. The influence of such surface modification on the stability of the resultant Pickering emulsions...

We investigate the adsorption dynamics of colloidal particles to a liquid/liquid interface. Such an analysis is important in the formation of Pickering emulsions. Using a free energy formulation that has been used for adsorption of surfactants, we obtain the time evolution of the surface coverage and dynamic surface tension. We estimate the characteristic time for adsorption, and show that it c...

Core-shell microcapsules are typically made by preparing an emulsion and forming a polymer shell around the droplets. Conventionally, the emulsion is stabilised by surfactants or polymers. Alternatively, emulsions can be stabilised by fine particles; we discuss capsules made from ultrafine kaolin stabilised Pickering emulsions via interfacial polymerisation. This approach has a number of potent...

The manufacturing of stable emulsion is a very important challenge for the cosmetic industry, which has motivated intense research activity replacing conventional molecular stabilizers with colloidal particles. These allow minimizing hazards and risks associated use stabilizers, providing enhanced stability to obtained dispersions. Therefore, particle-stabilized emulsions (Pickering emulsions) ...

A new approach to synthesis of cross-linked colloidosomes (microcapsules with a shell from colloidal particles) was developed on the basis of a peroxidized Pickering emulsion (an emulsion stabilized exclusively by peroxidized colloidal particles). Peroxidized latex particles were employed to ensure formation of Pickering emulsion. Free radical polymerization was used to convert droplets of a pe...