Field trials carried out upon the second more poisonous compound, bis dimethylamino fluoro phosphine oxide, proved its exceptional effectiveness as an insecticide and since an economic process for its manufacture had been developed and a ready sale of the product was assured, there was ample incentive for its early manufacture. Moreover, the plant erected earlier for the small-scale manufacture...

Wastewater Treatment Facilities have been built to remove biological and chemical waste from water as it is used. These facilities maintain a healthy environment for organisms as well as people because it removes potentially harmful material and kills pathogens that would easily spread through cities. Phosphorus is a compound of interest because a high concentration of it at discharge will even...

Becke-Göhring and Boppel [1] studied the reaction of hexachlorocyclotriphosphazene, N3P3CI6 with ethylenediamine and isolated the tetrachloro(ethylenediamino) derivative, NaPsCMNHCHaCHaNH) to which an ansa type structure (chlorine atoms replaced from two phosphorus atoms) was assigned [2, 3]. A reinvestigation of the reaction has been reported recently [4] and a spirocyclic structure (1) (chlor...

Alzheimer's disease (AD), characterized by progressive cognitive decline, is the most prevalent neurodegenerative disease in the elderly. Cerebral β-amyloid (Aβ) deposition is the major pathological hallmark of AD. Recent studies also have shown that the serum level of phosphorus correlates to the risk of incident dementia. To date, the linkage between cerebral Aβ deposition and the serum phosp...

This thesis explores the potential of zinc, cobalt, and phosphorus to influence primary production in the subarctic North Pacific, the Bering Sea, and the North Atlantic Ocean. In the North Pacific and Bering Sea, total zinc concentrations were measured along a near-surface transect and in selected deep profiles. Zinc speciation was also measured with a novel anodic stripping voltammetry method...

Reaction of substituted-aniline (8) with ethyl (l-methyl-5-nitroimidazole-2- carbonyl) acetate (9) gave 4-hydroxy-2-(l-methyl-5-nitro-2-imidazolyl)- substituted-quinolines (lo), which were converted to compound 11 with phosphorus oxychloride. Substituted-2-(l-methyl-5-nitro-2-imidazo1yl)-4.- methyl-(or phenyl-) quinolines (14) were prepared through the reaction of 2- acetyl-5-nitro-1-methy...

The phosphonate-phosphate rearrangement is an isomerisation of α-hydroxyphosphonates bearing electron-withdrawing substituents at the α-carbon atom. We studied the stereochemical course of this rearrangement with respect to phosphorus. A set of four diastereomeric α-hydroxyphosphonates was prepared by a Pudovik reaction from two diastereomeric cyclic phosphites. The hydroxyphosphonates were sep...

A mutant of Neurospora crassa, called UW-6, differs from wild type in being partially constitutive for synthesis of a species of alkaline phosphatase, and also for a species of phosphate permease that has a high affinity for phosphate at high pH. UW-6 is possibly allelic with a mutant called nuc-2 that was previously isolated by Ishikawa. nuc-2 has the converse phenotype, in that it cannot be d...