The effects of different types and concentrations of electron donors (glucose, starch, methanol and sodium acetate) on the formation of phosphine from anaerobic activated sludge that has been domesticated for a prolonged period were studied in small batch experiments. The results show that types and concentrations of electron donor have significant effects on the production of phosphine from an...

The objectives of this work were to assess phosphine resistance in insect populations (Tribolium castaneum, Rhyzopertha dominica, Sitophilus zeamais and Oryzaephilus surinamensis) from different regions of Brazil and to verify if the prevailing mechanism of phosphine resistance in these populations involves reduced respiration rates. Sixteen populations of T. castaneum, 15 of R. dominica, 27 of...

The red flour beetle is a cosmopolitan pest of stored grain and stored grain products. The pest has developed resistance to phosphine, the primary chemical used for its control. The reproductive output of survivors from a phosphine treatment is an important element of resistance development but experimental data are lacking. We exposed mated resistant female beetles to 0.135 mg/L of phosphine f...

The manufacture and application of aluminium phosphide fumigants pose risks of inhalation exposure to phosphine gas. This article presents a case report of suspected inhalation exposure to phosphine gas in a manufacturing facility for aluminium phosphide fumigants, which was associated with acute dyspnoea, hypotension, bradycardia and other signs of intoxication. These symptoms resolved within ...

background: aluminum phosphide (alp) poisoning is one of the most life threatening emergencies. in this study, demographic characteristics, clinical profiles and outcomes of a series of patients presented with alp poisoning in north iran are described. methods: the study was a retrospective descriptive medical chart review of alp poisoned patients who were admitted to internal ward of imam khom...

Phosphine-catalyzed tandem Michael addition/intramolecular Wittig reactions have been developed for the synthesis of chiral 2,5-dihydro-1H-pyrrole and tetrahydropyridine derivatives. These processes rendered catalytic in phosphine, thanks to situ reduction phosphine oxide by phenylsilane. Furthermore, asymmetric P(III)/P(V) were implemented using enantiopure phosphines.

Catalytic synthesis of nonracemic P-chiral phosphine derivatives remains a significant challenge. Here we report Cu-catalyzed enantioselective arylation of secondary phosphine oxides with diaryliodonium salts for the synthesis of tertiary phosphine oxides with high enantiomeric excess. The new process is demonstrated on a wide range of substrates and leads to products that are well-established ...

U.S. exported lettuce, broccoli, asparagus, and strawberries oftenharborwesternßower thrips, Frankliniella occidentalis (Pergande) (Thysanoptera: Thripidae), a quarantined pest in Taiwan, and therefore require quarantine treatment. Fumigation with diluted pure phosphine at a low temperatureof 2 Cwas studied to controlwesternßower thrips and todetermineeffects on thequality of the treated produc...

Gas-chromatographic analysis of the volatile compounds in the headspace of cultures inoculated with sewage sludge indicated phosphine production over a period of several days, a reaction which is clearly microbiologically mediated. The amounts of phosphine recovered from 40-mL specimens sewage sludge enrichment were in a pg-range of 5 to 100 in the presence of glucose as carbon source and phosp...

Phosphine metal-organic frameworks (P-MOFs) are crystalline porous coordination polymers that contain phosphorus functional groups within their pores. We present the use of X-ray absorption spectroscopy (XAS) at the P K-edge to determine the phosphine to phosphine oxide ratio in two P-MOFs with MIL-101 topology. The phosphorus oxidation state is of particular interest as it strongly influences ...