In this work, the effects of permeate pressure and feed flow rate on the performance of a composite polyvinyl alcohol (PVA) membrane in the removal of benzene from gasoline by pervaporation (PV) were evaluated. The results indicate the remarkable effect of permeate pressure on membrane performance as reducing permeate pressure (higher vacuum) from 30 to 3 mmHg causes the total flux to increase ...

The effects of operating parameters such as feed temperature and permeate-side pressure on the performance of a commercial PVA membrane in the dehydration of toluene by a pervaporation (PV) membrane system is studied in the present work. The results obtained indicate that increasing temperature in the range of 40 to 70 °C and reducing permeate pressure in the range of 1 to 10 mmHg increase memb...

Since membrane separations, such as vapor permeation (VP) or pervaporation (PV), are not limited by vapor-liquid equilibrium, their coupling with distillation can exert a synergistic effect, overcome the thermodynamic limits of distillation, and improve energy efficiency, especially suitable for separation azeotropic mixtures that otherwise requires special processes. Therefore, there is an inc...

Pervaporation (PV) has attracted increasing attention because of its potential application in bio-butanol recovery from fermentation process. In this work, PDMS/ceramic composite membrane was employed for PV separation of acetone–butanol–ethanol (ABE) aqueous solutions. The influence of coupling effect on the molecular transport during the PV process was systematically investigated. The separat...

The development of processes based on the integration of new technologies is of growing interest to industrial catalysis. Recently, significant efforts have been focused on the design of catalytic membrane reactors to improve process performance. In particular, the use of membranes, that allow a selective permeation of water from the reaction mixture, positively affects the reaction evolution b...

Thin film composite (TFC) membranes of the prototypical polymer intrinsic microporosity (PIM-1) have been prepared by dip-coating on a highly porous electrospun polyvinylidene fluoride (PVDF) nanofibrous support. Prior to coating, support was impregnated in non-solvent avoid penetration PIM-1 inside PVDF network. Different non-solvents were considered and results compared with those dry When ap...

This report summarizes the findings of an evaluation of the cross-flow pervaporation technology developed by ZENON Environmental, Inc. (ZENON). This evaluation was conducted under the U.S. Environmental Protection Agency (EPA) Superfund Innovative Technology Evaluation (SITE) Program. The ZENON pervaporation technology was demonstrated over a 5-day period in February 1995 at Naval Air Station N...

A zeolite NaA (LTA) membrane supported by an alumina porous support tube for pervaporation (PV) dehydration of ethanol was characterized by transmission electron microscopy (TEM) using a focused ion beam (FIB) thin-layer specimen preparation technique and by Fourier transform infrared attenuated total reflectance method (FTIR-ATR) using a diamond prism as the waveguide. FIB-TEM clearly presente...

Pervaporation (PV) has shown great potential in the separation of butanol aqueous solutions due to their economic and environmental benefits. This work applies polydimethylsiloxane (PDMS) composite membrane separate four isomers (n-butanol, isobutanol, sec-butanol tert-butanol) solution. Based on physical chemical properties isomers, such as solubility, polarity interaction parameter, we system...

As an alternative energy source to fossil fuels, biobutanol has received increasing attention. In this work, new mixed matrix membranes (MMMs) incorporating zeolitic imidazolate frameworks (ZIF-71) particles into polyether-block-amide (PEBA) were prepared for biobutanol recovery from acetone–butanol–ethanol (ABE) fermentation broth by pervaporation (PV). FESEM, EDS, XRD, FT-IR, DSC and contact ...