نتایج جستجو برای: pentachlorophenol
تعداد نتایج: 1289 فیلتر نتایج به سال:
The crystal structure of Escherichia coli nitrate reductase A (NarGHI) in complex with pentachlorophenol has been determined to 2.0 A of resolution. We have shown that pentachlorophenol is a potent inhibitor of quinol:nitrate oxidoreductase activity and that it also perturbs the EPR spectrum of one of the hemes located in the membrane anchoring subunit (NarI). This new structural information to...
The dissociation constants of the following substituted phenols in 50 wt percent methanol have been measured at 25 °C: o-nitrophenol, p-nitrophenol, 4-methyl-2-nitrophenol, 2,6-di chlorophenol , pentachlorophenol. The respective values found, expressed as pK values, are 7.91" 7.692 , 8.28" 7.680 , and 5.27.. The dissociation cons tants of 4-methyl-2-nitrophenol and pentachlorophenol, again exp ...
several authors have indicated that pcp is a toxic chemical and recalcitrant to biodegradation. aops is one of the moste effective process for degradation of persistant compound.since the mineralization of recalcitrant compound by aops (advanced oxidation processes) often requires long reaction time and strong doses of oxidant, the combination of this process with biological one, considered as ...
background: phenol and its derivatives like dinitrophenol and pentachlorophenol (carbolic acid) are widely used as insecticides, but they are very toxic substances. phenol is a general protoplasmic poison with corrosive local effects that denature proteins. poisoning with phenol compounds may occur by ingestion, inhalation, and absorption through skin. in this report we presented the toxicity e...
Density functional theory (DFT) calculations based on the BLYP-D4 and PBEh-3c composite methods were performed for investigating encapsulation mode of pentachlorophenol (PCP) inside cavity β-cyclodextrin (β-CD). Different quantum chemical parameters such as HOMO, LUMO, HOMO–LUMO gap calculated. Complexation energies computed at molecular level to provide insight into inclusion PCP β-CD cavity. ...
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