A new method is proposed for naphthalene extraction and spectrophotometric determination of palladium at the ppm level with chinoform. The method is based on the formation of a yellow complex which is extractable by molten naphthalene and on the dissolution of the extract in dioxane. The yellow solution follows Beer's law at 462 nm over ~he range of 7 to 140 ~g of palladium per 10 ml of dioxane...

Formation of green coloured ternary complexes between palladium, chromeazurol S and cetyltrimethylammonium bromide or cetylpyridinium bromide is described over the pH range 4.6 to 5.6. The compositions, Pd(CAS)CTA2 and Pd(CAS)CP2 for the ternary complexes have been established by Job's method of continuous variations and by the mole ratio method using absorbance data. Strict control of experime...

The use of N-11-octylaniline in xylene for extraction of palladium(II) from salicylate media is studied. The extraction system is studied as a function of equilibration time, diluent, pH, metal and extractant concentrations. Experimental data have been analyzed graphically to determine the stoichiometry of extracted species. It was found that palladium(II) was extracted into the organic phase b...

Palladium(II) complexes carrying chromophoric tropos ligands show a characteristic UV change and strong Cotton effects upon coordination of amino alcohols or diamines. The distinct (chir)optical responses can be used for instantaneous in situ determination of the concentration and ee of diamines and amino alcohols at low concentrations.

A simple, rapid and efficient dispersive liquid–liquid microextraction by use of ionic liquid (IL-DLLME)method, followed by flame atomic absorption spectrometry (FAAS) was developed for the preconcentrationand determination of palladium in water samples. In this method, an appropriate mixture of acetone and octylmethyl imidazolium hexafluorophosphate was injected rapidly into the aqueous sample...

A flameless atomic absorption method for the coextraction of platinum and palladium from biological and environmental samples by high molecular weight amine (HMWA) is given. Also, methods for lead determination in biological samples by use of extraction flameless analysis and direct aspiration-flame analysis are reported. A study of lead contamination of Vacutainer tubes is given.

Series of chiral palladium(II) allyl and cinnamyl complexes bearing a C1-symmetric N-heterocyclic carbenes were synthesized from achiral precursors. The chirality theses results the formation carbene-palladium bond which restricts rotation dissymmetric N-aryl substituents NHC thus creates an axis chirality. Chiral HPLC at preparative scale enabled resolution racemic provided straightforward acc...