Paper spray (PS) ambient ionization is implemented using a portable mass spectrometer and applied to the detection of alkyl quaternary ammonium salts in a complex oil matrix. These salts are commonly used as active components in the formulation of corrosion inhibitors. They were identified in oil and confirmed by their fragmentation patterns recorded using tandem mass spectrometry (MS/MS). The ...

A new method for the synthesis of industrially important azoimidazolium dyes is presented. The procedure is based on a reagent which is rarely used in the context of synthetic organic chemistry: nitrous oxide ("laughing gas"). N2O is first coupled to N-heterocyclic carbenes. Subsequent reaction with aromatic compounds through an AlCl3-induced C-H activation process provides azoimidazolium dyes ...

background: toluene is a volatile organic compound, one of 189 hazardous air pollutants (hap s ) and the most important pollutant found in most industries and indoor environments; owing to its adverse health, toluene must be treated before being released into the environment. methods : in this research study, a continuous-flow system (including an air compressor, silica gel filters and activate...

The majority of all biologically caused taste-and-odor outbreaks in drinking water characterized worldwide are caused by microbial production of ( )-geosmin [( )-(4S,4aS,8aR)-4,8adimethyloctahydronaphthalen-4a-ol] and ( )-2-methylisoborneol (2-MIB) {(1R-exo)-1,2,7,7-tetramethylbicyclo[2.2.1]heptan-2-ol}. Since they were first identified in the early 1960s, these two earthy-muddy-smelling metabo...

background: volatile organic compounds (vocs) are human-made chemicals widely spread in the environment and produced by petrochemical industries and petroleum refineries. the aim of this research was to evaluate the distribution of vocs in the ambient air of mahshahr petrochemical complex, iran. methods: this study was a cross-sectional research performed in 2009. we used the method numbered 15...

Rotating-bomb calorimetry was first applied to organic compounds that contain chlorine, bromine, or sulphur. Techniques developed for these classes of compounds, mostly at the University of Lund and at the Bureau of Mines in Bartlesville, have been described in the book Experimental Thermochemistry-, The development of rotating-bomb methods made accurate combustion calorimetry feasible for othe...

the difficult to handle and store zinc borohydride, zn(bh4)2, is stabilized by supporting it on polyvinylpyridine. this new mild, efficient, selective, and regenerable polymer supported borohydride reducing agent reduces a variety organic compounds such as, aldehydes, a-b-unsaturated carbonyl compounds, acid chlorides, epoxides, disulfides, as well as reductive acetylation of carbonyl compounds...

Citation: Wünsch UJ, Murphy KR and Stedmon CA (2015) Fluorescence Quantum Yields of Natural Organic Matter and Organic Compounds: Implications for the Fluorescence-based Interpretation of Organic Matter Composition. Front. Mar. Sci. 2:98. doi: 10.3389/fmars.2015.00098 Fluorescence Quantum Yields of Natural Organic Matter and Organic Compounds: Implications for the Fluorescence-based Interpretat...