We study the configurational structure of the point-island model for epitaxial growth in one dimension. In particular, we calculate the island gap and capture zone distributions. Our model is based on an approximate description of nucleation inside the gaps. Nucleation is described by the joint probability density p(n)(XY)(x,y), which represents the probability density to have nucleation at pos...

In this paper, we provide a theoretical basis using thermodynamic stability analysis for explaining the spontaneous nucleation and growth of a high density of 1-D structures of a variety of materials from low-melting metals such as Ga, In, or Sn. The thermodynamic stability analysis provides a theoretical estimate of the extent of supersaturation of solute species in molten metal solvent. Using...

Binary heterogeneous nucleation of watersuccinic/glutaric/malonic/adipic acid on nanometer-sized particles is investigated within the frame of classical heterogeneous nucleation theory. Homogeneous nucleation is also included for comparison. It is found that the nucleation probabilities depend on the contact angle and on the size of the seed particles. New thermodynamical properties, such as sa...

amyloid-β (aβ) self-assembly into cross-β amyloidfibrils is implicated in a causative role in alzheimer’s disease pathology.uncertainties persist regarding the mechanisms of amyloid self assembly and the role of metastable prefibrillar aggregates. aβ fibrilsfeature a sheet-turn-sheet motif in the constituent β-strands; as such, turn nucleation has been proposed as a rate-limiting step in the se...

Homogeneous nucleation at high supersaturation of vapor and heterogeneous nucleation on microscopic wettable particles are studied on the basis of Lennard-Jones model system. A hybrid classical thermodynamics and density-functional theory (DFT) approach is undertaken to treat the nucleation problems. Local-density approximation and weighted-density approximation are employed within the framewor...

Experimental results on bubble nucleation in the solid-state polystyrene–nitrogen system are presented. It was found that the bubble nucleation occurs over a period of approximately 30 s, and is not instantaneous as previously suggested. Over the range of nitrogen pressures explored, 4–14 MPa, the cell nucleation density increased exponentially. However this increase was many orders of magnitud...

This article reviews recent ­ ndings on internal and surface nucleation in silicate glasses. The internal homogeneous nucleation rates sharply decrease and the induction times increase with the Tg=TL ratio (Tg is the glass-transition temperature and TL is the liquidus temperature). Only systems that have Tg=TL < 0:58 display measurable internal nucleation rates on a laboratory time-scale. Numer...

We present new experimental data of the low-temperature metastable region of liquid water derived from high-density synthetic fluid inclusions (996-916 kg m-3) in quartz. Microthermometric measurements include: (i) prograde (upon heating) and retrograde (upon cooling) liquid-vapour homogenisation. We used single ultrashort laser pulses to stimulate vapour bubble nucleation in initially monophas...

Through in situ indentation of TiN in a high-resolution transmission electron microscope, the nucleation of full as well as partial dislocations has been observed from {001} and {111} surfaces, respectively. The critical elastic strains associated with the nucleation of the dislocations were analyzed from the recorded atomic displacements, and the nucleation stresses corresponding to the measur...

High-speed video and infrared thermometry were used to obtain timeand space-resolved information on bubble nucleation and heat transfer in pool boiling of water. The bubble departure diameter and frequency, growth and wait times, and nucleation site density were directly measured for a thin, electrically-heated, indium-tin-oxide surface, laid on a sapphire substrate. These data are very valuabl...