In this study, human feces were hydrothermal liquefied and converted into biocrude over Ni-Tm/TiO2 catalyst. The influence of catalysts, reaction temperature, and holding time on the distribution of products and element content of biocrude was assessed. The biocrude yield increased to 53.16% with a reaction temperature of 330 °C, a holding time of 30 min, and adding Ni-Tm/TiO2 catalyst while th...

Bimetallic Cu-Ni/TiO2 photocatalysts were synthesized using wet impregnation (WI) method with TiO2 (Degussa-P25) as support and calcined at different temperatures (180, 200, and 300°C) for the photodegradation of DIPA under visible light. The photocatalysts were characterized using TGA, FESEM, UV-Vis diffuse reflectance spectroscopy, fourier transform infrared spectroscopy (FTIR) and temperatur...

Light absorbers with moderate band gaps (1-2 eV) are required for high-efficiency solar fuels devices, but most semiconducting photoanodes undergo photocorrosion or passivation in aqueous solution. Amorphous TiO2 deposited by atomic-layer deposition (ALD) onto various n-type semiconductors (Si, GaAs, GaP, and CdTe) and coated with thin films or islands of Ni produces efficient, stable photoanod...

Hydrothermal and non-hydrothermal spherical TiO2 nanoporous with crystalline framework were prepared by sol-gel method. The Crystalline structures, morphologies and surface texturing of materials were determined by X-ray diffraction (XRD), scanning electron microscopy (SEM) and N2 adsorption-desorption isotherms. The Hydrothermal spherical TiO2 nanoporous was found to have a narrow and strong p...

Abstract Recently alcohol fuel cells has been increased consideration because of their environmental friendliness, high energy conversion efficiency and low emissions. Many effort have been made to improve the electro-oxidation performance of alcohols such as methanol, ethanol and propanol. In this work, a new method for ethanol oxidation based on core–shell titanium dioxide / carbon nanofib...

The nucleation and growth of Co clusters on vacuum-annealed (reduced) and oxidized TiO2(110) have been studied by scanning tunneling microscopy (STM), X-ray photoelectron spectroscopy (XPS), and density function theory (DFT) calculations. On vacuum-annealed TiO2(110), the Co clusters grow as three-dimensional islands at coverages between 0.02 and 0.25 ML, but the cluster heights range from ∼3 t...

The chemoselective continuous gas phase (T = 573 K; P = 1 atm) hydrogenation of nitroarenes (p-chloronitrobenzene (p-CNB) and m-dinitrobenzene (m-DNB)) has been investigated over a series of oxide (Al2O3 and TiO2) supported Au and Ni-Au (1 : 10 mol ratio; 0.1-1 mol% Au) catalysts. Monometallic supported Au with mean particle size 3-9 nm promoted exclusive formation of p-chloroaniline (p-CAN) an...

In the present study, composite layer double hydroxide-metal oxide (Ni/Al-TiO2 and Ni/Al-ZnO) was successfully prepared used as catalyst of oxidative desulfurization dibenzothiophene. Characterization XRD, FTIR, SEM-EDS. The structure Ni/Al-LDH, TiO2, ZnO in Ni/Al-TiO2 Ni/Al-ZnO consistent, which also indicated that preparation did not change form precursors. FTIR spectra absorption band at 339...