In this study, novel nanostructures based on Ni-MOF/polysulfone nanofibers were fabricated by microwave-assisted electrospinning method. The final fibrous nanostructure immobilized SiO 2 substrates with high physicho-chemical properties. These an average diameter of 20 nm and a specific surface area 1690 m /g used as adsorption for CH 4 gas adsorption. It seems that the integration Ni-MOF compo...

As an important subclass of metal-organic frameworks (MOFs), homochiral MOFs show special ability of asymmetric catalysis and enantioselective separation via the open chiral channels or cavities. A new homochiral MOF membrane [Ni2(mal)2(bpy)]•2H2O (Ni-MB) was synthesized by a secondary growth technique, in which high energy ball milling was employed to prepare nanosized MOF seeds, and their syn...

The utilization of the electrode materials for supercapacitor based on metal-organic frameworks (MOFs) has gained much attraction from researchers, due to their remarkable surface area, tunable pore size, and numerous redox sites. construction a hierarchical Ni-MOF/graphene oxide (GO) incorporated graphene nanoplatelet (GNP) exhibited unique synergistic interaction between two different graphit...

The highly porous and robust [Ni(8)(OH)(4)(OH(2))(2)(4,4'-(buta-1,3-diyne-1,4-diyl)bispyrazolato)(6)](n) MOF can be used as a proof of concept for the incorporation and release of the non-conventional [Ru(p-cymene)Cl(2)(pta)] RAPTA-C metallodrug.

In this work, we have demonstrated the generation of dissipative soliton from single to multi-pulsing phenomenon. The ultrashort pulses was achieved with nickel-based metal organic framework (Ni-MOF) as saturable absorber in a ring cavity erbium-doped fiber laser. SA fabricated by spin-coating Ni-MOF/polydimethylsiloxane composite on tapered substrate, which had an insertion loss 2.82 dB, modul...

Lignin is an attractive renewable source of aromatics with a low effective hydrogen to carbon ratio (H/Ceff). The catalytic hydrodeoxygenation (HDO) lignin-derived model compounds key strategy for lignin upgrading. In this work, the HDO guaiacol, typical compound, was carried out over metal–organic framework (MOF)-derived Ni-based catalysts. A monometallic Ni-MOF catalyst and different ratios b...

Understanding the molecular mechanism of proton conduction is crucial for the design of new materials with improved conductivity. Quasi-elastic neutron scattering (QENS) has been used to probe the mechanism of proton diffusion within a new phosphonate-based metal-organic framework (MOF) material, MFM-500(Ni). QENS suggests that the proton conductivity (4.5 × 10(-4) S/cm at 98% relative humidity...

We present a first principles study of low-spin (LS)/high-spin (HS) screening for 3d metal centers in the metal organic framework (MOF) DUT-8(Ni). Various density functional theory (DFT) codes have been used to evaluate numerical and DFT related errors. We compare highly accurate all-electron implementations with the widely used plane wave approach. We present electronically and magnetically st...

Ni functionalized metal organic frameworks (MOF) are promising heterogeneous ethene dimerization catalysts. Activities comparable to or higher than Ni-aluminosilicates have been reported in literature. However, unlike the Ni-aluminosilicates, those Ni-MOFs require a large excess of co-catalyst initiate process and some catalysts generate polymers which lead catalyst deactivation. Herein, we rep...

In this manuscript, we have developed an efficient spraying method to successfully fabricate a series of flower-like coordination polymers (CP) microparticles, including Co/BDC (1,4-benzenedicarboxylate) metal organic frameworks (MOF) and infinite coordination polymers (ICP) microparticles, as well as Ni-Co/BDC MOF and Zn/DOBDC (2,5-dioxido-1,4-benzenedicarboxylate) MOF. The spraying method has...