The depolymerization of lignin to bioaromatics usually requires a hydrodeoxygenation (HDO) step to lower the oxygen content. A mixed Cu-Mg-Al oxide (CuMgAlO x ) is an effective catalyst for the depolymerization of lignin in supercritical ethanol. We explored the use of Ni-based cocatalysts, i.e. Ni/SiO2, Ni2P/SiO2, and Ni/ASA (ASA = amorphous silica alumina), with the aim of combining lignin de...

Ni nanowires are synthesized by template based electrochemical technique. A commercially available filter membrane of alumina anodic oxide (AAO) is used for the fabrication of nanowires. AAO membrane supported on copper substrate yields better hexagonal nanowires. Morphological studies of nanowires are carried out using scanning electron microscopy (SEM). The analysis shows the fabrication of v...

A combined method of laser ablation (LA) and ICP-MS has gained much attention as a direct analytical method for solid samples. The determination of some elements, however, is seriously disturbed by isobaric interferences, mainly caused by argon and ambient air constituents. The use of low-pressure helium-ICP is a promising solution of the problem. A 1:1 mixture of alumina powder and glycerol wa...

Aluminium oxide (Al2O3), commonly known as alumina, is a widespread naturally occurring compound that has a broad range of industrial applications. Besides its use as a pigment or abrasive, alumina also plays a vital role as catalyst support for desulfurization or hydrogenation reactions. In the latter case, the active phase on the catalyst often consists of nickel metal nanoparticles. The inte...

In an Al2O3-TiO2 mixed oxide system, the incorporation of TiO2 to alumina is known to increase the acidity of the resulting mixed oxide; depending strongly on the preparation method and the titania concentration. When using TiO2 as a support of NiMo catalysts, initial catalytic activity in hydrodesulfurization reactions is much higher than that on catalysts based on pure alumina. One of the mai...

A sensitive open-type calorimeter was used to measure excess heat production during electrolysis in Li2SO4/H2O solution with Pt-anode and Pd-Ni thin film cathodes 9000 Å thick, sputtered on Al2O3 substrate. In order to estimate the actual performance and possible measurement errors during electrolysis in the calorimeter used, including heat convection, bubbling and possible H2+O2 recombination,...

Biodiesel which were synthesis from transesterification reaction in the present of heterogeneous base catalyst has been intensively studied over the last decades. This catalyst has an excellent result in producing high percentage conversions of biodiesel without further purification and cleaning process which contribute to the water pollution and high water content in biodiesel product. So, thi...

Ni-based catalysts supported on alumina derived from the pseudo-boehmite prepared by impregnation method were employed for catalytic dry reforming of methane reaction at temperature 550–750 °C. The effect calcination physicochemical properties such as Ni dispersion, reduction degree, nickel crystallite sizes, and metal–support interaction was investigated. characterization results show that inc...

Nickel oxides supported on ?-alumina (Ni-loading from 5 to 30 wt% NiO) have been synthesized and tested in the oxidative dehydrogenation (ODH) of ethane order determine importance NiO-support interaction. The best performance was achieved by catalyst with 15 NiO; higher NiO-loadings lead formation unselective bulk-like NiO lower Ni-loadings present high proportion free alumina surface sites. pr...