The rates of hydrolysis of TrEE, TEE, and ATEE(1) by alpha-chymotrypsin were determined in media of variable dielectric strength. Many substances which modify the dielectric constant of the medium, exert additional specific effects on the reaction rate, noticeable at more or less elevated concentrations. Notwithstanding, it is possible to differentiate the dielectric and specific effects by com...

Molecular simulations of strongly coupled dipolar systems of varying size have been carried out, using particles confined inside a dielectric cavity and an image charge approach to treat the dielectric response from the surroundings. A simple method using penalty functions was employed to create an isotropic and homogeneous distribution of particles inside the cavity. The dielectric response of...

We consider an oblate Bose-Einstein condensate of heteronuclear polar molecules in a weak applied electric field. This system supports a rich quasiparticle spectrum that plays a critical role in determining its bulk dielectric properties. In particular, in sufficiently weak fields the system undergoes a polarization wave rotonization, leading to the development of textured electronic structure ...

In this study, we investigate the transparency of an overdense inhomogeneous plasma slab. This anomalous transmission is achieved when the conditions provided for the incident electromagnetic wave to excite coupled surface waves on the both sides of the slab. These conditions require that the homogeneous overdense plasma, or the metallic film, is placed between two dielectric layers. Here, the ...

the oil-paper insulation is a type of an inexpensive combination insulation system in oil-filled power transformers. in this study the dielectric and strength properties of canola oil and mineral oil impregnated hand-sheet papers were investigated. all hand sheets were made of unbleached bagasse soda pulp with two different freeness levels of 200 ± 25 ml, csf and 400± 25 ml,csf. after drying th...

In an implicit-solvent description of molecular solvation, the electrostatic free energy is given through the electrostatic potential. This potential solves a boundary-value problem of the Poisson-Boltzmann equation in which the dielectric coefficient changes across the solute-solvent interface-the dielectric boundary. The dielectric boundary force acting on such a boundary is the negative firs...

The refractive index of a dielectric medium comprising both passive and inverted components in its permittivity was determined using two methods: (i) in the time domain, a finite–difference algorithm to compute the frequency–domain reflectance from reflection data for a pulsed plane wave that is normally incident on a dielectric half–space, and (ii) in the frequency domain, the deflection of an...

The properties of the filamentary microdischarges found in dielectric barrier discharges depend on the manner of charging of the dielectric. The charging of the dielectric removes voltage from the gap thereby reducing E/N and producing a transition from an avalanching discharge to a recombination or attachment dominated discharge. In this article, we report on a computational investigation of t...