bis-(l-tyrosinato)copper(ii) was reacted with 3-(chloropropyl)-trimethoxysilane functionalized silica that has infused magnetite to yield a magnetically separable catalyst in which the copper carboxylate is covalently linked to the silica matrix through the silane linkage. the immobilized catalyst has been characterized by spectroscopic studies (such as ft-ir, epr, magnetic measurement, sem) an...

fe3o4 magnetic nanoparticles were synthesized by co-precipitation of fe2+ and fe3+ in aqueous naoh. then silica was coated on the obtained nanoparticles and the whole composite was functionalized with chlorosulfonic acid in ch2cl2. the obtained nanocomposite (fe3o4@sio2-so3h) was characterized by ft-ir, vsm and xrd techniques and was used as an efficient catalyst in condensation reaction of ind...

a simple highly versatile and efficient sonochemical synthesis of 1,2,4,5-tetrasubstituted and 2,4,5-trisubstituted imidazoles is achieved by condensation of 1,2-dicarbonyl compound, aldehyde, ammonium acetate and primary amine using antimony trichloride immobilized on silica gel (sio2-osbcl2) as a catalyst in ethanol at moderate temperature. operational simplicity, practicability and applicabi...

Nanomagnetic NiFe2O4 was used as the efficient, stable, reusable catalyst for selective oxidation of alcohols to their corresponding carbonyl compounds using oxone (potassium hydrogen monopersulfate) as oxidant in the presence of water as solvent at room temperature. The oxidation of various primary and secondary alcohols has been examined and related corresponding products were obtained wi...

Nanomagnetic MgFe2O4 is an active, stable, and reusable catalyst for the oxidation of alcohols. The oxidation of various primary and secondary alcohols has been examined and related corresponding products were obtained in good yields. The reactions were carried out in the presence of water as solvent and oxone (at room temperature) or H2O2 (at 60 ºC) as an oxidant. The catalyst was investigated...

A theory is presented for how magnetic nanostructures can catalyze intersystem crossing in molecular radical pairs. Magnetic field gradients near physically realistic nanostructures are strong enough to induce a relative reorientation of two electronic spins in <1 ns, overwhelming nuclear hyperfine coupling as a driver of intersystem crossing. Nanomagnetic control of intersystem crossing repres...

cellulose bonded n-propyl diethylene tetra sulfamic acid (cbpdetsa) was successfully applied as a green and recyclable acidic catalyst for the synthesis of tetrahydrobenzo [a] xanthene-11-one as an important class of potentially bioactive compounds. the products are obtained by the coupling of 2-naphtol , cyclohexadione and aldehyde derivatives in good to high yields (70- 92%) under solvent-fre...

Meysam Yarie was born in 1987 in Malayer/ Hamedan, Iran. He received his B.Sc. in Applied Chemistry (2010) from Malek-Ashtar University of Technology and M.Sc. in Organic Chemistry (2012) from Kurdistan University under the supervision of Dr. Kamal Amani. He is currently working towards his Ph.D. under the supervision of Professor Mohammad Ali Zolfigol. His research interest is the synthesis, c...

A long-standing goal of computer technology is to process and store digital information with the same device in order to implement new architectures. One way to accomplish this is to use nanomagnetic logic gates that can perform Boolean operations and then store the output data in the magnetization states of nanomagnets, thereby doubling as both logic and memory. Unfortunately, many of these na...

Bis-(L-tyrosinato)copper(II) was reacted with 3-(chloropropyl)-trimethoxysilane functionalized silica that has infused magnetite to yield a magnetically separable catalyst in which the copper carboxylate is covalently linked to the silica matrix through the silane linkage. The immobilized catalyst has been characterized by spectroscopic studies (such as FT-IR, EPR, Magnetic Measurement...