Nanocomposite membranes composed of polymer and inorganic nanoparticles are a novel method to enhance gas separation performance. In this study, membranes were fabricated from polysulfone (PSf) containing magnesium oxide (MgO) nanoparticles and gas permeation properties of the resulting membranes were investigated. Membranes were prepared by solution blending and phase inversion methods. Morpho...

The objective of this work is to develop a new class of nanocomposite ultrafiltration (UF) membranes with excellent solute rejection rate and superior water flux using zeolitic imidazolate framework-8 (ZIF-8) and multi-walled carbon nanotubes (MWCNTs). The effect of ZIF-8 and MWCNTs loadings on the properties of polyvinyldifluoride (PVDF)-based membrane were investigated by introducing respecti...

The introduction of sulfonic acid modified silica in Nafion nanocomposite membranes is a good method of improving the Nafion performance at high temperature and low relative humidity. Sulfonic acid-modified silica is bifunctional, with silica phase expected to offer an improvement in membranes hydration while sulfonic groups enhance proton conductivity. However, as discussed in this paper, this...

Over the past decade, many applications were intended for filtration by membrane technology especially the thin film composite (TFC) membranes. In advanced developments of thin film membranes, an attempt was made to spread a new generation of membranes called thin film nano composite (TFN) membranes. However, in the last generation of TFNs, an ultrathin selective film of nanoparticles is coated...

1387-1811/$ see front matter 2012 Elsevier Inc. A http://dx.doi.org/10.1016/j.micromeso.2012.03.052 ⇑ Corresponding authors. E-mail addresses: [email protected] (C.W. Jo ch.edu (S. Nair). The effect of typical membrane processing conditions on the structure, interfacial morphology, and gas separation performance of MOF/polymer nanocomposite membranes is investigated. In particular, the ZIF...

Metal nanoparticles are known as highly effective catalysts although their immobilization on solid supports is frequently required to prevent aggregation and to facilitate the catalyst application, recovery, and reuse. This paper reports the intermatrix synthesis of Pd0 nanoparticles in sulfonated polyethersulfone with Cardo group membranes and their use as nanocomposite catalytic membrane reac...

The surface properties of TiO2-PVDF nanocomposite membranes were investigated by incorporating different chemically modified TiO2 nanoparticles into the poly (vinylidene fluoride) (PVDF) matrix. The nanocomposite membranes were prepared via dual coagulation bath diffusion and the induced phase inversion method. The membrane surface morphologies were investigated by using SEM and AFM and related...

Direct methanol fuel cells (DMFCs) are considered to be one of the most promising candidates for portable and stationary applications in the view of their advantages such as high energy density, easy manipulation, high efficiency and they operate with liquid fuel which could be used without requiring any fuel-processing units. Electrolyte membrane of DMFC plays a key role as a proton conductor ...

Polymer nanocomposites continue to receive tremendous attention for application in areas such as microelectronics, organic batteries, optics, and catalysis. We have discovered that physical dispersion of nonporous, nanoscale, fumed silica particles in glassy amorphous poly(4-methyl-2-pentyne) simultaneously and surprisingly enhances both membrane permeability and selectivity for large organic m...