BACKGROUND Metalloporphyrin ions, with planar shape, have been known to intercalate horizontally and diagonally between montmorillonite layers. Perpendicular intercalation inside montmorillonite has not been reported earlier. This work aims at achieving perpendicular intercalation inside montmorillonite in natural clays. Possible intercalation inside other forms of natural clay will also be inv...

nowadays, titanium-based alloys are among the most attractive metallic materials for biomedical applications (as implants) due to their non-biodegradability, low density, good mechanical properties as well as their good biocompatibility. hydroxyapatite (ca10 (po4)6(oh)2, ha) has been widely used for biomedical applications due to its bioactive, biocompatible and osteoconductive properties. firs...

conducting polymers, because of their special properties, are used to introduce conductive polymeric composites. also, clays have recently been used for preparation of polymer composites with enhanced mechanical and thermal properties. the aim of this work is to study the synergetic effect of the co-presence of conducting polyaniline and montmorillonite in the polyethylene matrix. polyethylene ...

Polymer-clay nano-composite materials, in which nano-meter thick layers of clay dispersed in polymer matrix, have generally higher mechanical properties than normal polymeric materials. A new three-dimensional unit cell model has been developed for modeling three constituent phases including inclusion, interphase and matrix. The total elastic modulus of nano-composite is evaluated.  Numerical r...

Polymer-clay nano-composite materials, in which nano-meter thick layers of clay dispersed in polymer matrix, have generally higher mechanical properties than normal polymeric materials. A new three-dimensional unit cell model has been developed for modeling three constituent phases including inclusion, interphase and matrix. The total elastic modulus of nano-composite is evaluated.  Numerical r...

Nano ZnO/ montmorillonite composite were prepared by sol gel method under ultrasonic irradiation from directly mixing montmorillonite nano clay into Zinc gel. The Zn(CH3COO)2.2H2O and montmorillonite nano clay was used as precursor. The zinc acetate was dissolved in DI water and, NH3 (aq) solution was dropped into the zinc solution until pH 9 consequently the zinc gel was produced. The montmori...

Effects of nano-clay on weight loss of wood-plastic composites (WPC) by five fungi were studied. Nanoclay particles of 20 to 50 nm size were applied at 2, 4, and 6% WPC of 0,90 g/cm3 density. The white-rot fungi Physisporinus vitreus, Pleurotus ostreatus and Trametes versicolor as well as the brown-rot species Antrodia vaillantii and Coniophora puteana were used. Mass loss tests were conducted ...

Clay-based nanostructured multilayers, such as clay-polymer multilayers and clay-oxide multilayers, have attracted growing attention owing to their remarkable mechanical properties and promising application in various fields. In this paper, synthesis of a new kind of nanostructured clay-oxide multilayers by layer-by-layer self-assembly was explored. Nano-mechanical characterization of 18 clay-b...