The use of Monte Carlo simulation to predict the adsorption of mixtures of polar and nonpolar species on acti®ated carbon was in®estigated using water and ethane on BPL carbon as a prototype system. The structure of the adsorbent was modeled by an array of slit-shaped pores, characterized by a pore-size distribution. The chemical heterogeneity of the carbon was taken into account by including o...

For a multicomponent competitive adsorption of furfural and phenolic compounds, a mathematical model was builtto describe the mass transfer kinetics in a fixed bed column with activated carbon. The effects of competitive adsorption equilibrium constant, axial dispersion, external mass transfer, and intraparticle diffusion resistance on the breakthrough curve were studied for weakly adsorbed com...

among various reported membrane-based gas separation processes, the best explanation is generally achieved by the solution-diffusion model. the main factors in this model are the solubility and diffusivity of permeationcomponents through the membrane. the prediction of permeability and diffusivity in multicomponent gas permeation as well as the separation evaluation equilibrium and kinetic inte...

In this work spent coffee grounds from single-use capsules were used as the starting material for producing low-cost activated carbons. The activation conditions were selected and optimised to produce microporous carbons with high CO2 adsorption capacity and selectivity, thus with potential to be used as adsorbents in postcombustion CO2 capture applications. Two activation methods are compared:...

Chromatographic measurements were made for the adsorption of benzene, toluene and m-xylene on molecular sieving carbon (MSC) in supercritical fluid CO2 mixed with organics. Supercritical chromatograph packed with MSC was used to detect pulse responses of organics. Adsorption equilibria and adsorption dynamics parameters for organics were obtained by moment analysis of the response peaks. Depend...

The MIT Faculty has made this article openly available. Please share how this access benefits you. Your story matters. Abstract This paper presents the first instance of a double contact discontinuity in analytical solutions for multicomponent, two-phase flow in porous media. We use a three-component system with constant equilibrium ratios and fixed injection and initial conditions, to demonstr...