نتایج جستجو برای: modeling of modified electrode
تعداد نتایج: 21226352 فیلتر نتایج به سال:
A novel chemically modified electrode containing Prussian blue complex was achieved on the surface of glass carbon electrode by sol-gel technique. The electrochemical behavior of modified electrode was characterized by cyclic voltammetry in detail. The film electrode obtained was very stable and exhibited electrocatalytic response for oxidation of nitrite. Results showed at bare GC electrode, a...
A selective electrochemical method for the determination of uric acid was developed by using nano poly cresol red modified glassy carbon electrode. This new material has been characterized by Scanning Electron Microscopy, cyclic voltammetry and Differential pulse voltammetry. This modified electrode shows excellent electrocatalytic activity towards the oxidation of uric acid in the presence of ...
Oxidation of formaldehyde (HCHO) is very important, owing to its use in fuel cells. Modification of electrodes surfaces is an excellent way to decrease the overpotentials as well as to increase the current density of the voltammetric response.pt as most efficient metal catalyst can easily be poisoned by product of oxidation and also it has high cost. In this work an efficient and low cost elect...
this is an original study on the effect of a polyisobutylene – polydimethylsiloxane (pibpdms) block copolymer modifier used as an interfacial active agent on the dynamics behaviour of single newtonian drops suspended in a polyisobutylene (pib) newtonian matrix. the results were divided in two sections. the first part included the experiments carried out on the non-modified and 2% block cop...
a one dimensional dynamic model for a riser reactor in a fluidized bed catalytic cracking unit (fccu) for gasoil feed has been developed in two distinct conditions, one for industrial fccu and another for fccu using various frequencies of microwave energy spaced at the height of the riser reactor (fccu-mw). in addition, in order to increase the accuracy of component and bulk diffusion, instanta...
this paper describes the development, electrochemical characterization and utilization of novel modified molybdenum (vi) complex-carbon nanotube paste electrode for the electrocatalytic determination of ascorbic acid (aa). the electrochemical profile of the proposed modified electrode was analyzed by cyclic voltammetry (cv) that showed a shift of the oxidation peak potential of aa about 235 mv ...
A novel chemically modified electrode was constructed based on multi-walled carbon nanotubes, MCM48 molecular sieve composite modified glassy carbon electrode .The modified electrode showed that it can be used for simultaneous determination of acetaminophen (ACT) and codeine (COD), simultaneously. The measurements were carried out by the application of differential pulse voltammetry (DPV), cycl...
in this work, sol-gel method was used tosynthesize titanium dioxide nanoparticles (tio2). the tio2nanoparticles was characterized by scanning electron microscopy (sem), x-ray diffraction (xrd) and bet technique.the tio2 and coumarin derivative (7-(1,3-dithiolan-2-yl)-9, 10-dihydroxy-6h-benzofuro [3,2-c] chromen-6-on) were incorporated in a graphite composite electrode. the resulting modified el...
Fabrication and electrochemical characterization of a sensor for the determination of epinephrine (EP), uric acid (UA) and folic acid (FA) is described. The sensor was prepared using carbon paste electrode (CPE) modified with 3,4-dihydroxybenzaldehyde-2,4-dinitrophenylhydrazone (DDP) and carbon nanotubes (CNTs), which makes the modified electrode highly sensitive for the electrochemical detect...
a carbon-past electrode modified with iron(ii) phathalocyanine (fepc) was used as a sensitive potentiometric sensor for determination of 2-pyridinethiol (2pt). 2-mercaptoethanol (2me) and sulfide ion in aqueous solutions. the modified electrode acts as an electrocatalyst for oxidation of these compounds, and lowers the overpotential for oxidation reactions by more than 400 mv, compared to the u...
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