A simple and precise incremental isoconversional integral method based on Li-Tang (LT) method is proposed for kinetic analysis of solid thermal decomposition, in order to evaluate the activation energy as a function of conversion degree. The new method overcomes the limitation of LT method in which the calculated activation energy is influenced by the lower limit of integration. By applying the...

The thermal degradation of poly(methyl methacrylate) (PMMA) has been studied in both pure nitrogen and oxygen-containing atmospheres. The presence of oxygen increases the initial decomposition temperature by 70 °C. The stabilizing effect of oxygen may be explained by forming thermally stable radical species that suppress unzipping of the polymer. This assumption is supported by the experimental...

in this work, thermal degradation behavior of a fuel-rich energetic mixture containing epoxy binder was studied by thrmogravimetric analysis and differential scanning calorimetry under dynamic nitrogen atmosphere at different heating rates. variation of the thermal degradation activation energy of the mixture was evaluated by differential and integral isoconversional methods via akts software p...

This review covers both the history and present state of the kinetics of thermally stimulated reactions in solids. The traditional methodology of kinetic analysis, which is based on ® tting data to reaction models, dates back to the very ® rst isothermal studies. The model ® tting approach suŒers from an inability to determine the reaction model uniquely, and this does not allow reliable mechan...

in this paper, installment options on the underlying assetwhich evolves according to black-scholes model and pays constant dividendto its owner will be considered. applying arbitrage pricing theory,the non-homogeneous parabolic partial differential equation governingthe value of installment option is derived. then, penalty method is usedto value the european continuous installment call option.

Isoconversional analysis is a model-free and powerful approach that readily provide quantitative information of the kinetics thermally activated transformation. Activation energy preexponential factor are main output isoconversional analysis. Another practical application kinetic predictions computed in way. In this communication, computational tool predicting nonisothermal presented. This dire...