Theoretical computation of the pressure dependence superconducting state parameters of binary Ca60Al40 is reported using model potential formalism. Explicit expressions have been derived for the volume dependence of the electron–phonon coupling strength λ and the Coulomb pseudopotential μ* considering the variation of Fermi momentum KF and Debye temperature ӨD with volume. Well known Ashcroft’s...

The controllability over strongly correlated electronic states promises unique electronic devices. A recent example is an optically induced ultrafast switching device based on the transition between the correlated Mott insulating state and a metallic state of a transition metal dichalcogenide 1T-TaS2. However, the electronic switching has been challenging and the nature of the transition has be...

Direct experimental evidence of half-metallic density of states (DOS) is observed by scanning tunneling spectroscopy on ferromagnetic La0.7Ca0.3MnO3, which exhibits colossal magnetoresistance (CMR). Tunneling conductance data taken at 77 K, well below the Curie temperature TC ø 260 K, show close resemblance to the spin-split DOS spectrum calculated for the itinerant bands in the ferromagnetic s...

The evolution of the short-range structural signature of the Ir4+ dimer state in CuIr2S4 thiospinel has been studied across the metal-insulator phase transitions as the metallic state is induced by temperature, Cr doping, and x-ray fluence. An atomic pair distribution function (PDF) approach reveals that there are no local dimers that survive into the metallic phase when this is invoked by temp...

Reports of metallic behavior in two-dimensional (2D) systems such as high mobility metal-oxide field effect transistors, insulating oxide interfaces, graphene, and MoS2 have challenged the well-known prediction of Abrahams, et al. that all 2D systems must be insulating. The existence of a metallic state for such a wide range of 2D systems thus reveals a wide gap in our understanding of 2D trans...

The evolution from the metallic (or plasmonic) to molecular state in metal nanoparticles constitutes a central question in nanoscience research because of its importance in revealing the origin of metallic bonding and offering fundamental insights into the birth of surface plasmon resonance. Previous research has not been able to probe the transition due to the unavailability of atomically prec...