Prelithiated, electrospun α-Fe2O3 nanofibers display an exceptional cycleability when it is paired with commercial LiMn2O4 cathode in full-cell assembly. The performance of such α-Fe2O3 nanofibers is mainly due to the presence of unique morphology with porous structure, appropriate mass balance, and working potential. Also, synthesis technique cannot be ruled out for the performance.

electronic and magnetic structures in the LiMn2O4 spinel David Santos-Carballal, 2, ∗ Phuti E. Ngoepe, and Nora H. de Leeuw 3, † School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, United Kingdom Materials Modelling Centre, School of Physical and Mineral Sciences, University of Limpopo, Private Bag x 1106, Sovenga, 0727, South Africa Department of Earth Science...

Aqueous lithium energy storage systems address environmental sustainability and safety issues. However, significant capacity fading after repeated cycles of charge-discharge and during float charge limit their practical application compared to their nonaqueous counterparts. We introduce an artificial solid electrolyte interphase (SEI) to the aqueous systems and report the use of graphene films ...

A wide range (y = 0.05—0.33) of Co-doped LiCo5Mn2_504 spinels were synthesized and electrochemically characterized. These Co-doped spinels showed improved specific capacity and capacity retention over pure spinels. Electrochemical impedance spectroscopy and the linear polarization resistance technique were used to determine the transport and electrochemical kinetic parameters of Co-doped spinel...

In situ measurements of the hydrothermal formation of LiMn2O4 (LMO) nanocrystallites reveal that the reaction progresses in steps, each creating a different crystalline phase. The reaction route is summarized as KMnO4→disordered δ-MnO2→(ordered δ-MnO2)→LiMn2O4→(γ-Mn2O3)→Mn3O4. The phase purity of LMO can be controlled by reaction time and temperature where phase pure LMO is obtained after 150-2...

We demonstrate that extensive electrochemical shock–electrochemical cycling induced fracture–occurs due to coherency stresses arising from first order cubic-to-cubic phase transformations in the spinels LiMn2O4 and LiMn1.5Ni0.5O4. Electrochemical shock occurs despite the isotropy of the shape changes in these materials. This electrochemical shock mechanism is strongly sensitive to particle size...

Li-rich layered Li1+xMnyM1-x-yO2 (or denoted xLi2MnO3·(1 -x)LiMO2, M = Ni, Co, Mn, etc.) are promising cathode materials for high energy-density Li-ion batteries. However, their commercial applications suffer from problems such as a drop in the capacity and discharge voltage during cycling. In this work, the cycling performance of a layered oxide Li1.2Ni0.13Co0.13Mn0.54O2 is improved by integra...

Intercalation-electrode materials are electroactive and serve as host solids into which guest species are reversibly intercalated from an electrolyte. Currently there are three intercalation materials that are used commercially as positive-electrode materials in lithium-ion rechargeable batteries: LiCoO2, LiNiO2, and LiMn2O4. LiCoO2 is the most popular among the possible cathode materials becau...